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E14403

Ethyl α-bromoisobutyrate

Name: Ethyl α-bromoisobutyrate
Brand: ALDRICH

98%

Synonym(s):

Ethyl 2-bromo-2-methylpropionate

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About This Item

Linear Formula:

(CH₃)₂CBrCOOC₂H₅

CAS Number:

600-00-0

Molecular Weight:

195.05

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24894409

EC Number:

209-980-6

Beilstein/REAXYS Number:

1098947

MDL number:

MFCD00000123

Assay:

98%

Form:

liquid

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Properties

Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.444 (lit.)

bp

65-67 °C/11 mmHg (lit.)

density

1.329 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)C(C)(C)Br

InChI

1S/C6H11BrO2/c1-4-9-5(8)6(2,3)7/h4H2,1-3H3

InChI key

IOLQWGVDEFWYNP-UHFFFAOYSA-N

Description

General description

Ethyl α-bromoisobutyrate is an organic bromoester used as an initiator in controlled radical polymerization reactions.

Application

Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with an ethyl end group.

pictograms

GHS02,GHS05,GHS07

signalword

Danger

hcodes

H226,H302,H318

pcodes

P210 - P233 - P240 - P280 - P301 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

140.0 °F - closed cup

flash_point_c

60 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Articles

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Facile fabrication of a controlled polymer brush-type functional nanoprobe for highly sensitive determination of alpha fetoprotein.

Na Wang et al.

Analytical methods : advancing methods and applications, 12(36), 4438-4446 (2020-08-29)

As robust functional polymers, polymer brush-based hybrid nanomaterials have potential application in the highly sensitive determination of tumor markers (TMs). Currently, there are plentiful reports on the polymerization methods of functional polymer brushes. Low ppm ATRP (activators (re)generated by electron

The Strengthening and Toughening of Biodegradable Poly (Lactic Acid) Using the SiO2-PBA Core-Shell Nanoparticle.

Hailing He et al.

Materials (Basel, Switzerland), 12(16) (2019-08-10)

The balance of strengthening and toughening of poly (lactic acid) (PLA) has been an intractable challenge of PLA nanocomposite development for many years. In this paper, core-shell nanoparticles consisting of a silica rigid core and poly (butyl acrylate) (PBA) flexible

Synthesis of the N-methyl Derivatives of 2-Aminothiazol-4(5H)-one and Their Interactions with 11βHSD1-Molecular Modeling and in Vitro Studies.

Renata Studzińska et al.

Chemistry & biodiversity, 16(6), e1900065-e1900065 (2019-04-24)

11β-Hydroxysteroid dehydrogenase type 1 (11β-HSD1) is an enzyme that affects the body's cortisol levels. The inhibition of its activity can be used in the treatment of Cushing's syndrome, metabolic syndrome and type 2 diabetes. In this study, we synthesized new

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Global Trade Item Number

SKU	GTIN
E14403-100G	04061833601815
E14403-500G	04061836696344
E14403-5G	04061833601822