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Merck
CN

205869

乙酸钯(II)

98%, reagent grade, powder

别名:

Pd(OAc)2

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关于此项目

线性分子式:
Pd(OCOCH3)2
化学文摘社编号:
分子量:
224.51
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
222-164-4
MDL number:
Beilstein/REAXYS Number:
6086766
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产品名称

乙酸钯(II), reagent grade, 98%

grade

reagent grade

Quality Level

assay

98%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

216.3-223.7 °C (dec.)

SMILES string

CC(O[Pd]OC(C)=O)=O

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

General description

[Pd(OAc)2]3 是一种钯配位络合物,也是一种多相金属催化剂,它被广泛用于有机合成中,比如转移金属化、插入反应、氧化加成反应、芳基卤化物的直接均偶联、 形成C-N的Buchwald-Hartwig 反应、炔烃的还原和还原消除反应。它还可用作合成其他 Pd(II)化合物的起始材料,以及制备用于Suzuki-Miyaura交叉偶联和C-H官能化反应的活性钯催化剂。

Application

[Pd(OAc)2]3 可被用作:
  • 催化剂,用于末端和内部炔烃的区域选择性抗氢氯化反应。
  • 前体,用于制备Heck偶联反应和Sonogashira交叉偶联反应用的非均相钯络合物催化剂。


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signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

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商品

Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.

相关内容


Mark McLaughlin et al.
Organic letters, 8(15), 3311-3314 (2006-07-14)
[Structure: see text] An efficient regioselective method for the preparation of structurally diverse imidazopyridinones and benzoimidazolones starting from readily available and economical starting materials is described. High-yielding reductive alkylation of electron-deficient o-haloarylamines followed by treatment with inexpensive N-chlorosulfonyl isocyanate afforded
Mark S Chen et al.
Journal of the American Chemical Society, 126(5), 1346-1347 (2004-02-05)
Sulfoxide ligation to Pd(II) salts is shown to selectively promote C-H oxidation versus Wacker oxidation chemistry and to control the regioselectivity in the C-H oxidation products. A catalytic method for the direct C-H oxidation of monosubstituted olefins to linear (E)-allylic
Ikuyo Kamiya et al.
The Journal of organic chemistry, 70(2), 696-698 (2005-01-18)
A highly regioselective hydroselenation of terminal alkynes with benzeneselenol can be achieved by the combination of palladium acetate and pyridine, providing the corresponding terminal alkenes, (i.e., 2-phenylseleno-1-alkenes) as a sole product. In this hydroselenation, pyridine may act as a suitable



全球贸易项目编号

货号GTIN
205869-100G04061833301418
205869-10G04061835508556
205869-1G04061835554522
205869-25G04061835521234
205869-2G04061835554539