208671
双三苯基膦二氯化钯
98%, solid
别名:
PdCl2(PPh3)2, 三苯基膦氯化钯, 二氯二(三苯基膦)钯(II)
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关于此项目
线性分子式:
[(C6H5)3P]2PdCl2
化学文摘社编号:
分子量:
701.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
237-744-2
MDL number:
Beilstein/REAXYS Number:
4935975
产品名称
双三苯基膦二氯化钯, 98%
Quality Level
assay
98%
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
SMILES string
Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4
InChI
1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI key
YNHIGQDRGKUECZ-UHFFFAOYSA-L
General description
二（三苯基膦）二氯化钯(II)((PdCl2(PPh3)2) 是一种含有叔膦配体的有机钯络合物，常用于C-C键形成反应，如Heck芳基化、Suzuki偶联、Stille偶联和Sonogashira 偶联。
Application
二（三苯基膦）二氯化钯(II)可用作以下反应的催化剂：
- 2-碘苯甲醚和末端炔烃偶联合成 2,3-二取代苯并呋喃的反应。
- 用于合成二苯乙炔的无铜Sonogashira 交叉偶联反应
- 苯乙烯的区域选择性氢羧基化。
- 氟芳基特戊酸锌的Negishi偶联以制备氟化寡苯（fluorinated oligophenyl）。
- 烃的碘-α-β-未取代酯的偶联以生成四取代烯。
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signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 4 - Skin Sens. 1A
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
相关内容
Alison B Lemay et al.
The Journal of organic chemistry, 71(9), 3615-3618 (2006-04-22)
The efficient regioselective and stereospecific synthesis of tetrasubstituted olefins using a mild and convenient method is disclosed. 2-Alkynyl esters are selectively converted to E-beta-chloro-alpha-iodo-alpha,beta-unsaturated esters by exposure to Bu4NI in refluxing dichloroethane. These products are produced cleanly, regio- and stereoselectively
Nannan Jian et al.
Physical chemistry chemical physics : PCCP, 21(13), 7174-7182 (2019-03-20)
Conjugated fluorophores have been extensively used for fluorescence sensing of various substances in the field of life processes and environmental science, due to their noninvasiveness, sensitivity, simplicity and rapidity. Most existing conjugated fluorophores exhibit excellent light-emitting performance in dilute solutions
Ganesan Bharathiraja et al.
Organic & biomolecular chemistry, 13(9), 2786-2792 (2015-01-22)
Various tetrasubstituted pyrroles/pyrazoles have been prepared from nitro-substituted 1,3-enynes with aromatic amines/hydrazines via a copper-catalyzed cascade aza-Michael addition, cyclization and aromatization at room temperature. This protocol is also effective for the synthesis of tetrasubstituted pyrazoles in high yields.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 208671-5G | 04061838770141 |
| 208671-100G | 04061838770110 |
| 208671-1G | 04061838770127 |
| 208671-25G | 04061838770134 |