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569747

Grubbs Catalyst® M204

solid, Umicore

别名:

(1,3-双(2,4,6-三甲基苯基)-2-咪唑烷亚基)二氯(邻异丙氧基苯亚甲基)合钌, 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌, Grubbs Catalyst® M2a (C848), Grubbs Catalyst®第2代催化剂, 二氯(1,3-二(2，4，6-三甲苯基)2-imidazolidinylidene](苯亚甲基)(三环己基膦)钌(II)

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关于此项目

经验公式（希尔记法）:
C46H65Cl2N2PRu
化学文摘社编号:
246047-72-3
分子量:
848.97
MDL number:
MFCD03453237
UNSPSC Code:
12352302
PubChem Substance ID:
329758255
NACRES:
NA.22
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产品名称

Grubbs Catalyst® M204, Umicore

product line

Grubbs Catalyst® M200 Series

form

solid

reaction suitability

core: ruthenium
reaction type: Olefin Metathesis, reagent type: catalyst
reaction type: Ring-Opening Polymerization

manufacturer/tradename

Umicore Grubbs Catalyst® M200 Series

mp

143.5-148.5 °C

storage temp.

2-8°C

SMILES string

CC(C=C(C)C=C1C)=C1N2CCN(C3=C(C)C=C(C)C=C3C)C2[Ru](P(C4CCCCC4)(C5CCCCC5)C6CCCCC6)(Cl)(Cl)=CC7=CC=CC=C7

InChI

1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2

InChI key

FCDPQMAOJARMTG-UHFFFAOYSA-L

Application

Grubbs Catalyst ® M204 可用于关环复分解（RCM）、交叉复分解和开环复分解聚合（ROMP）的催化剂。还可用于通过交叉复分解和关环复分解反应合成具有优异功能基团兼容性和选择性的三取代烯烃。
可用作催化剂：

  • 通过RCM反应从酚类化合物合成香豆素。
  • 裂解(E)-烯丙基vic-二醇成乙醛。
对于小规模和高通量应用，可选用ChemBeads形式(919764)

了解更多复分解催化剂

Other Notes

Aldrich用于烯烃复分解的Grubbs催化剂® 技术
第二代 569755 Hoveyda-Grubbs 催化剂®

Legal Information

Umicore 产品

产品许可证
该产品及其制造或使用受Umicore PMC拥有或控制的一项或多项已发布或正在申请的美国专利（和国外等同专利）权限管辖。通过Sigma-Aldrich、其关联公司或其授权分销商从Umicore PMC购买此产品，购买者将享受有限的一次性、非排他、不可转让、不可分配的许可。购买者使用此产品可能会侵犯第三方拥有或控制的专利。购买者应自行确保其使用产品未侵犯第三方专利权或超出本协议授予的许可范围。

有关产品的更多信息，请询当地Umicore PMC联系人，网址http://www.pmc.umicore.com。
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

pictograms

Flame
GHS02

signalword

Warning

hcodes

H228

Hazard Classifications

Flam. Sol. 2

存储类别

4.1B - Flammable solid hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCQ8583
MKCQ2914
MKCQ1675
MKCQ0620
MKCP0919

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相关内容

Grubbs Group – Prof. Product Portal

Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.

Olefin Metathesis Application Guide

The Olefin Application Metathesis Application Guide provides - The Key Features of Metathesis, General Reaction Procedures, Guidance for Choosing the Correct Metathesis Route, A Metathesis Quick Guide

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全球贸易项目编号

货号GTIN
569747-10G04061832597225
569747-100MG04061832597218
569747-25G04065270988423
569747-2G04061832597232
569747-500MG04061832597249