Key Documents

700703

N-tert-Butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylamine

Name: N-tert-Butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylamine
Brand: ALDRICH

Synonym(s):

2,2,5-Trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane, Alkoxyamine NMP initiator

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About This Item

Empirical Formula (Hill Notation):

C₂₂H₃₁NO

CAS Number:

227000-59-1

Molecular Weight:

325.49

NACRES:

NA.23

PubChem Substance ID:

329762224

UNSPSC Code:

12162002

MDL number:

MFCD12546017

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Properties

form

liquid

Quality Level

100

refractive index

n20/D 1.536

density

0.968 g/mL at 25 °C

storage temp.

−20°C

SMILES string

CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2

InChI

1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3

InChI key

FPFRTDOMIFBPBZ-UHFFFAOYSA-N

Description

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Application

Block Copolymer Synthesis Using a Commercially Available NMP Inititator

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Articles

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Benoit, D., Chaplinski, V., Braslau, R., Hawker, C.J.

Journal of the American Chemical Society, 121, 3904-3904 (1999)

Global Trade Item Number

SKU	GTIN
700703-1G	04061826280386
700703-250MG	04061832978024