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Merck
CN

213462

Sodium borohydride

ReagentPlus®, 99%

Synonym(s):

Sodium tetrahydridoborate

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About This Item

Linear Formula:
NaBH4
CAS Number:
Molecular Weight:
37.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
241-004-4
MDL number:
Assay:
99%
Form:
powder
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Quality Level

product line

ReagentPlus®

assay

99%

form

powder

reaction suitability

reagent type: reductant

mp

>300 °C (dec.) (lit.)

SMILES string

[BH4-].[Na+]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

General description

Sodium borohydride, also known as sodium tetrahydridoborate, is a highly basic boron hydride that is commonly used as a reducing agent. It reacts very slowly with water and acts as a catalyst and stabilizer.

Application

Sodium borohydride can be used as a reducing agent for the:
  • Synthesis of cobalt (II, III) oxide (Co3O4) from cobalt chloride (CoCl2) via a co-reduction process.
  • Solvent-free reduction of aldehydes and ketones to alcohols in the presence of solid acid as an activator.
  • Reductive amination of carbonyl compounds to secondary amines in the presence of silica-gel-supported sulfuric acid as a catalyst.
  • Raney nickel-catalyzed reduction of aromatic nitro compounds to aromatic amines.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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signalword

Danger

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react. 1

Regulatory Information

监管及禁止进口产品

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Articles

纳米颗粒的溶剂热合成:从纳米电路、纳米光学电路到纳米磁学和生物技术应用。

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.


Dinesh Bhalothia et al.
Nanomaterials (Basel, Switzerland), 9(7) (2019-07-25)
Herein, ternary metallic nanocatalysts (NCs) consisting of Au clusters decorated with a Pt shell and a Ni oxide core underneath (called NPA) on carbon nanotube (CNT) support were synthesized by combining adsorption, precipitation, and chemical reduction methods. By a retrospective
Barbara Fogli et al.
Scientific reports, 9(1), 10095-10095 (2019-07-14)
While axons within the central nervous system (CNS) do not regenerate following injury, those in the peripheral nervous system (PNS) do, although not in a clinically satisfactory manner as only a small proportion of axons exhibit long-distance regeneration. Moreover, functional
Basavaiah, D. et al.
The Journal of Organic Chemistry, 64, 1197-1197 (1999)



Global Trade Item Number

SKUGTIN
213462-500G04061833498743
213462-100G04061838772855
213462-25G04061838772862