254274
Lithium hydroxide monohydrate
99.95% trace metals basis
Synonym(s):
Lithine hydrate
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About This Item
Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-183-4
MDL number:
Assay:
99.95% trace metals basis
Form:
crystalline
Quality Level
assay
99.95% trace metals basis
form
crystalline
reaction suitability
core: lithium
greener alternative product characteristics
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impurities
≤550.0 ppm Trace Metal Analysis
application(s)
battery precursors
catalysts
material synthesis precursor
greener alternative category
SMILES string
[Li+].O.[OH-]
InChI
1S/Li.2H2O/h;2*1H2/q+1;;/p-1
InChI key
GLXDVVHUTZTUQK-UHFFFAOYSA-M
General description
Lithium hydroxide monohydrate is a strongly alkaline crystalline solid soluble in water. It is prepared industrially by recovering it from spodumene or by evaporating a solution prepared by reacting calcium hydroxide and lithium carbonate. It is mainly used in the synthesis of cathode materials for lithium-ion batteries, such as lithium cobalt oxide (LiCoO2) and lithium iron phosphate. It is also preferred over lithium carbonate for producing lithium nickel manganese cobalt oxides.
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Application
Lithium hydroxide monohydrate can be used mainly for the synthesis of cathode materials for Lithium-ion batteries:
- To synthesize Olivine LiFePO4 nanoplates with different crystal orientations by glycol-based solvothermal process. It demonstrated that the crystal orientation of cathode nanoplates plays an important role in the performance.
- As a precursor for the synthesis of LiFePO4 platelets under hydrothermal synthesis conditions. It exhibited homogeneous particle size distribution, greater electrochemical performances and cycle life, and morphology control.
- To synthesize Ni-rich Li[NixCoyMn1–x–y]O2 gradient cathodes (NCM). These cathodes exhibited enhanced cycling and chemical stability due to their strong crystallographic texture, unique particle morphology, and highly correlated particle orientation.
- As a precursor to prepare porous salt hydrate-based composites for low-temperature thermochemical heat storage.
- As an electrolyte additive in lithium-ion batteries.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
危险化学品
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Articles
Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.
Viktoria V Sursyakova et al.
Electrophoresis, 39(8), 1079-1085 (2018-02-08)
Cyclodextrins (CD) form inclusion complexes with different "guests" owing to the fact that the shape of the CD molecule is a truncated cone with a hydrophobic cavity. The adducts of CD with metal complexes remain scantily explored. In this study
Maria Concetta Bruzzoniti et al.
Journal of chromatography. A, 1187(1-2), 188-196 (2008-02-29)
A new high performance ion chromatographic method has been developed for the separation of the nine chlorinated-brominated haloacetic acids (HAAs) that are the disinfection by-products of chlorination of drinking water, using a macrocycle-based adjustable-capacity anion-exchange separator column (IonPac Cryptand A1).
Kwang-Heon Kim et al.
Ultrasonics sonochemistry, 15(6), 1019-1025 (2008-05-09)
Nano-sized HT-LiCoO(2) powders were prepared by sonochemical synthesis in an aqueous solution of lithium hydroxide containing cobalt hydroxide at approximately 80 degrees C without any further heat treatment at high temperature. The effects of the LiOH concentration, oxidation conditions, ultrasound
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 254274-50G | 04061838138668 |
| 254274-10G | 04061838138651 |
| 254274-250G | 04061838252715 |