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Merck
CN

577030

Polypyrrole

greener alternative

conductivity 10-50 S/cm (pressed pellet)

Synonym(s):

PPy

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About This Item

CAS Number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
MDL number:
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description

Electrodes

Quality Level

form

solid

contains

proprietary organic sulfonic acid as dopant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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solubility

H2O: insoluble, organic solvents: insoluble

greener alternative category

SMILES string

[nH]1cccc1

InChI

1S/C4H5N/c1-2-4-5-3-1/h1-5H

InChI key

KAESVJOAVNADME-UHFFFAOYSA-N

General description

Polypyrrole (PPy) is a widely used highly conductive and highly stable heterocyclic polymer. It is majorly used in electrochemical applications. It is a cost-efficient conducting polymer that has a stable oxidation and high solubility in water. It exhibits a high degree of flexibility than polyaniline and has a density that facilitates a higher capacitance per unit volume.
PPy may be prepared by a standard electrochemical technique. It may also be prepared by reacting -napthalene sulfonic acid (NSA) and ammonium peroxo-disulfate in aqueous medium. The charges on the surfaces can be easily modified by doping the polymer during its synthesis. Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid have been reported. Lectrosensitivity and lower oxidation potential of PPy make it potentially useful for drug delivery, chemical sensors, batteries, ion selective electrodes, biosensor and biochemistry research.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product is used in energy conversion and storage, thus has been enhanced for energy efficiency. Click here for more information.

Application

Conductive additive for thermoplastics and thermosets. Polypropylene composites constitute the polymer electrolyte membrane fuel cell (PEMFC). Addition of PPy to polypropylene composites alters its conductivity.
PPy can be used for a variety of applications such as:
  • electrode materials for sensors used in electrocardiography (ECG)
  • formation of electrode material for a variety of energy storage applications
  • encapsulation of lithium sulfide (Li2S) as a high performance cathode material

PPy is mainly used in the fabrication of a variety of electrochemical devices, which include supercapacitors, chemical sensors, dye sensitized solar cells and lithium-ion batteries.
Conducting polymer.
Conductive additive for thermoplasitics and thermosets.

Packaging

Packaged in glass bottles

Other Notes

Stable up to at least 290°C in air


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Articles

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The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

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Conducting polymers with superhydrophobic effects as anticorrosion coating
Intelligent Coatings for Corrosion Control, 409-430 (2014)
In-situ encapsulation of nickel nanoparticles in polypyrrole nanofibres with enhanced performance for supercapacitor
Muhamad SU, et al.
Electrochimica Acta, 249(8), 9-15 (2017)
Electrochemistry of nucleic acids and proteins: towards electrochemical sensors for genomics and proteomics
Palecek E, et al.
Journal of Nanoscience and Nanotechnology, 1(1), 596-612 (2005)



Global Trade Item Number

SKUGTIN
577030-25G04061833599334
577030-5G04061832628899