676578
Bis(tri-tert-butylphosphine)palladium(0)
solid
Synonym(s):
Pd(t-Bu3P)2
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About This Item
Product Name
Bis(tri-tert-butylphosphine)palladium(0),
form
solid
Quality Level
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
greener alternative product characteristics
Catalysis
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Greener Alternative Product
mp
258-272 °C
greener alternative category
, Aligned
storage temp.
−20°C
SMILES string
[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI
1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
InChI key
MXQOYLRVSVOCQT-UHFFFAOYSA-N
General description
Application
- Catalyst for Suzuki coupling on a multisubstituted sp3-carbon (eq. 1)
- Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
- Catalyst for Negishi coupling reaction (eq. 3)
- Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
- Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
- Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
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Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
No data available
flash_point_c
No data available
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Protocols
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
Articles
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 676578-1G | 04061832748085 |
| 676578-250MG | 04061832748092 |