710733
2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide
Synonym(s):
1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide
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About This Item
refractive index
n20/D 1.515
density
0.953 g/mL at 25 °C
storage temp.
−20°C
SMILES string
CC(C)C(N([O])C(C)(C)C)c1ccccc1
InChI
1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3
InChI key
VGHCMXLEZFMZOZ-UHFFFAOYSA-N
General description
Application
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Ox. Liq. 3
Storage Class
5.1B - Oxidizing hazardous materials
wgk
WGK 3
flash_point_f
205.0 °F - closed cup
flash_point_c
96.1 °C - closed cup
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Protocols
We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.
We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
Articles
Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator
Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.