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Merck
CN

723037

2-Cyano-2-propyl dodecyl trithiocarbonate

97% (HPLC)

Synonym(s):

S-(2-Cyanoprop-2-yl)-S-dodecyltrithiocarbonate

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About This Item

Empirical Formula (Hill Notation):
C17H31NS3
CAS Number:
Molecular Weight:
345.63
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Quality Level

assay

97% (HPLC)

form

liquid

refractive index

n20/D 1.535

density

0.991 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C#N

InChI

1S/C17H31NS3/c1-4-5-6-7-8-9-10-11-12-13-14-20-16(19)21-17(2,3)15-18/h4-14H2,1-3H3

InChI key

QSVOWVXHKOQYIP-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

2-Cyano-2-propyl dodecyl trithiocarbonate is used as a RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylate, methacrylamide, and styrene monomers. It is also used as a Chain Transfer Agent (CTA).


pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Protocols

RAFT(可逆加成-断裂链转移)是一种活性自由基聚合反应,在有适合的连转移(RAFT)试剂存在下发生的非传统的取代单体自由基聚合反应。

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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Articles

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

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Jeonghun Lee et al.
Journal of controlled release : official journal of the Controlled Release Society, 304, 164-172 (2019-05-15)
A blood clot (thrombus) is formed as a final product of the hemostatic process with two major components, a mesh of cross-linked fibrin and platelets activated by high concentration of hydrogen peroxide (H2O2). Thrombus formation impedes blood flow to brain
Liqin Mei et al.
Journal of materials chemistry. B, 8(25), 5434-5440 (2020-06-13)
Zwitterionic polymers have attracted increasing attention due to their excellent fouling resistance ability and eco-friendliness. Yet, their non-degradability and hydrophilic nature limit their applications. In this study, we have prepared a novel surface-fragmenting hyperbranched copolymer with tertiary carboxybetaine ester (TCB)
Munziya Abutalip et al.
Langmuir : the ACS journal of surfaces and colloids, 35(25), 8389-8397 (2019-06-15)
In this work, we report the first molecular weight-controlled amphiphilic polybetaine synthesis using various hydrocarbons via reversible addition?fragmentation chain-transfer (RAFT) polymerization. The experimental separation of the alkyl aminocrotonate tautomers, which has been the subject of debate, was completed for the



Global Trade Item Number

SKUGTIN
723037-1G04061826280539
723037-5G04061832861012