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Merck
CN

276855

Dimethyl sulfoxide

anhydrous, ≥99.9%

Synonym(s):

DMSO

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About This Item

Linear Formula:
(CH3)2SO
CAS Number:
Molecular Weight:
78.13
EC Number:
200-664-3
UNSPSC Code:
12191502
PubChem Substance ID:
Beilstein/REAXYS Number:
506008
MDL number:
Assay:
≥99.9%
Grade:
anhydrous
Bp:
189 °C (lit.)
Vapor pressure:
0.42 mmHg ( 20 °C)
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grade

anhydrous

Quality Level

vapor density

2.7 (vs air)

vapor pressure

0.42 mmHg ( 20 °C)

assay

≥99.9%

form

liquid

autoignition temp.

573 °F

expl. lim.

42 %, 63 °F

impurities

<0.005% water

evapn. residue

<0.0005%

color

colorless

refractive index

n20/D 1.479 (lit.)

bp

189 °C (lit.)

mp

16-19 °C (lit.)

solubility

H2O: miscible (completely)

density

1.10 g/mL (lit.)

SMILES string

CS(C)=O

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3

InChI key

IAZDPXIOMUYVGZ-UHFFFAOYSA-N

General description

Dimethyl Sulfoxide is an apolar protic solvent that is generally used as a reaction medium and reagent in organic reactions.

Application

Dimethyl Sulfoxide may be used as an oxidant for the conversion of isonitriles into isocyanates. DMSO activated by oxalyl chloride can be used in the oxidation of long-chain alcohols to carbonyls.

Packaging

18 L, 200 L packaged in Pure-Pac® stainless steel containers; 100 mL, 250ml, 1 L, 2 L, 6×1 L packaged in Sure/Seal® bottles

Other Notes

The article number 276855-4X2L will be discontinued. Please order the single bottle 276855-2L which is physically identical with the same exact specifications.
For information on dimethyl sulfoxide miscibility, please visit the following link:
Dimethyl Sulfoxide Miscibility/Immiscibility Table
Pure-Pac® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.

Legal Information

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Disclaimer

Supercools easily and remelts slowly at room temperature. Solidified product can be re-liquified by warming to room temperature without detriment to the product.


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Storage Class

10 - Combustible liquids

flash_point_f

188.6 °F - closed cup

flash_point_c

87 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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Articles

TiO2 exhibits wide band gap semiconductor and memristor properties electronically, with high opacity and UV absorbance optically.


A Practical Synthesis of Isocyanates from Isonitriles: Ethyl 2-Isocyanatoacetate
Hoang VLe and Ganem B
Organic Syntheses, 89, 404-404 (2012)
The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals
Royal Society of Chemistry null
Dimethyl sulfoxide oxidations.
Epstein WW & Sweat FW.
Organic Syntheses, 67(3), 247-260 (1967)



Global Trade Item Number

SKUGTIN
276855-2L04061826186961
276855-6X1L04061837532238
276855-PZ04061823900768
276855-100ML04061837532207
276855-12X100ML04061826186596
276855-200L04061838151896
276855-20L-P204061826186923
276855-1L04061837532214
276855-250ML04061826186947