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328634

NMP

Name: NMP
Brand: SIAL

anhydrous, 99.5%

Synonym(s):

1-Methyl-2-pyrrolidone, N-Methyl-2-pyrrolidone, NMP

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About This Item

Empirical Formula (Hill Notation):

C₅H₉NO

CAS Number:

872-50-4

Molecular Weight:

99.13

NACRES:

NA.21

PubChem Substance ID:

57648684

UNSPSC Code:

12352005

EC Number:

212-828-1

MDL number:

MFCD00003193

Beilstein/REAXYS Number:

106420

Assay:

99.5%

Grade:

anhydrous

Bp:

202 °C (lit.), 81-82 °C/10 mmHg (lit.)

Vapor pressure:

0.29 mmHg ( 20 °C), 0.99 mmHg ( 40 °C)

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Properties

Product Name

1-Methyl-2-pyrrolidinone, anhydrous, 99.5%

grade

anhydrous

Quality Level

200

vapor density

3.4 (vs air)

vapor pressure

0.29 mmHg ( 20 °C), 0.99 mmHg ( 40 °C)

assay

99.5%

form

liquid

autoignition temp.

518 °F

expl. lim.

9.5 %

impurities

<0.005% water

refractive index

n20/D 1.47 (lit.)

pH

7.7-10.0 (20 °C, 100 g/L)

bp

202 °C (lit.), 81-82 °C/10 mmHg (lit.)

mp

−24 °C (lit.)

density

1.028 g/mL at 25 °C (lit.)

SMILES string

CN1CCCC1=O

InChI

1S/C5H9NO/c1-6-4-2-3-5(6)7/h2-4H2,1H3

InChI key

SECXISVLQFMRJM-UHFFFAOYSA-N

Description

Application

1-Methyl-2-pyrrolidinone may be used as a solvent in the following processes:

Preparation of 2-aryl and 2-alkyl benzothiazoles.
Ullmann coupling reaction of aryl halides and phenols to form Ullmann ethers in the presence of 2,2,6,6-tetramethylheptane-3,5-dione.
Stille cross-coupling reaction of aryl iodides with organostannanes catalyzed by Pd/C in the presence of copper iodide as cocatalyst.

Packaging

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Other Notes

Pure-Pac^® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.

Legal Information

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

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pictograms

GHS08,GHS07

signalword

Danger

hcodes

H315,H319,H335,H360D

pcodes

P202 - P261 - P264 - P302 + P352 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

195.8 °F - Pensky-Martens closed cup

flash_point_c

91 °C - Pensky-Martens closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Stille couplings catalyzed by palladium-on-carbon with CuI as a cocatalyst: Synthesis of 2-(4'-acetylphenyl)thiophene

Liebeskind LS and Pe?a-Cabrera E

Organic Syntheses, 77, 135-135 (2000)

Preparation of 1-methoxy-2-(4-methoxyphenoxy)benzene

Buck E and Song ZJ

Organic Syntheses, 82, 69-69 (2005)

Effects of additional multiwall carbon nanotubes on impact behaviors of LiNi_0.5Mn_0.3Co_0.2O₂ battery electrodes.

Le AV, et al.

Journal of Applied Physics, 118(8), 085312-085312 (2015)

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Global Trade Item Number

SKU	GTIN
328634-100ML	04061837533334
328634-1L	04061837533358
328634-250ML	04061837537417
328634-6X1L	04061826717684
328634-12X100ML	04061837533341
328634-200L	04061836608484
328634-2L	04061837533365
328634-4X2L	04061826717677
328634-50L-P2	04061838161536
328634-PH-20L-P2	04065268977750
328634-PZ	04061823901437