105228
1,1,1,3,3,3-六氟-2-丙醇
≥99%
别名:
HFP, 六氟异丙醇
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关于此项目
线性分子式:
(CF3)2CHOH
化学文摘社编号:
分子量:
168.04
UNSPSC Code:
12352104
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-059-4
Beilstein/REAXYS Number:
1841007
MDL number:
Assay:
≥99%
Quality Level
assay
≥99%
refractive index
n20/D 1.275 (lit.)
bp
59 °C (lit.)
mp
−4 °C (lit.)
density
1.596 g/mL at 25 °C (lit.)
functional group
fluoro, hydroxyl
SMILES string
OC(C(F)(F)F)C(F)(F)F
InChI
1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H
InChI key
BYEAHWXPCBROCE-UHFFFAOYSA-N
General description
1,1,1,3,3,3-六氟-2-丙醇是溶液相肽化学溶剂。这种高电离能力的氟化极性溶剂可在无路易斯酸催化剂的情况下，通过共价试剂促进傅-克烷基化反应。它还可提高铑(I)催化的醚键连接的炔基二烯的[4 + 2]分子内环加成反应，以及炔基乙烯基环丙烷的[5 + 2]环加成反应效率。1,1,1,3,3,3-六氟-2-丙醇结合过氧化氢可团簇催化环辛烯和1-辛烯的环氧化作用。
Application
1,1,1,3,3,3-六氟-2-丙醇可用于制备六氟醇官能化甲基丙烯酸酯聚合物。
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Repr. 2 - Skin Corr. 1A - STOT RE 2 Oral
target_organs
Central nervous system
存储类别
8B - Non-combustible corrosive hazardous materials
flash_point_f
No data available
flash_point_c
No data available
ppe
Faceshields, Gloves, Goggles
商品
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Hexafluoroalcohol-functionalized Methacrylate Monomers for Lithographic/Nanopatterning Materials.
Sanders DP, et al.
Material Matters, 6(1), 1-7 (2011)
Kinetic Studies of Olefin Epoxidation with Hydrogen Peroxide in 1, 1, 1, 3, 3, 3-Hexafluoro-2-propanol Reveal a Crucial Catalytic Role for Solvent Clusters.
Berkessel A and Adrio JA.
Advanced Synthesis & Catalysis, 346(2-3), 275-280 (2004)
Akio Saito et al.
The Journal of organic chemistry, 71(17), 6437-6443 (2006-08-12)
In fluorinated alcohols, the cationic Rh(I) species, which is derived from [Rh(COD)Cl]2 and AgSbF6, efficiently catalyzed intramolecular [4+2] cycloaddition reactions of ester-tethered 1,3-diene-8-yne derivatives. The catalytic system was also effective in intramolecular [5+2] cycloaddition reactions of ester-tethered omega-alkynyl vinylcyclopropane compounds.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 105228-100G | 04061837631610 |
| 105228-25G | 04061837631627 |
| 105228-2KG | 04061838251787 |
| 105228-500G | 04061837631634 |
| 105228-5G | 04061837631641 |