125113
2-氯-5-硝基苯甲酸
97%
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关于此项目
线性分子式:
ClC6H3(NO2)CO2H
化学文摘社编号:
分子量:
201.56
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-739-7
Beilstein/REAXYS Number:
1877474
MDL number:
Assay:
97%
Form:
powder
Quality Level
assay
97%
form
powder
mp
165-168 °C (lit.)
functional group
carboxylic acid, chloro, nitro
SMILES string
OC(=O)c1cc(ccc1Cl)[N+]([O-])=O
InChI
1S/C7H4ClNO4/c8-6-2-1-4(9(12)13)3-5(6)7(10)11/h1-3H,(H,10,11)
InChI key
QUEKGYQTRJVEQC-UHFFFAOYSA-N
General description
2-Chloro-5-nitrobenzoic acid undergoes microwave-assisted, regioselective amination reaction with aliphatic and aromatic amines to yield N-substituted 5-nitroanthranilic acid derivatives. It acts as ligand and forms a red luminescent one dimensional coordination polymer with Eu(III).
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
2-Chloro-5-nitrobenzoato complexes of Eu (III) and Tb (III)-A 1D coordination polymer and enhanced solution luminescence.
Viswanathan S and Bettencourt-Dias A.
Inorganic Chemistry Communications, 9(5), 444-448 (2006)
Younis Baqi et al.
The Journal of organic chemistry, 72(15), 5908-5911 (2007-06-26)
The synthesis of N-substituted 5-nitroanthranilic acid derivatives 3a-w was achieved by a new, mild, microwave-assisted, regioselective amination reaction of 5-nitro-2-chlorobenzoic acid (1a) with a diverse range of aliphatic and aromatic amines 2a-w without added solvent or catalyst. Up to >99%
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 125113-500G | 04061838723345 |
| 125113-100G | 04061838723338 |