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126179

9,10-二氢蒽

Name: 9,10-二氢蒽
Brand: ALDRICH

97%

别名:

Dihydroanthracene

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关于此项目

经验公式（希尔记法）:

C₁₄H₁₂

化学文摘社编号:

613-31-0

分子量:

180.25

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24847705

EC Number:

210-336-1

Beilstein/REAXYS Number:

1364575

MDL number:

MFCD00001239

Assay:

97%

Form:

solid

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属性

Quality Level

100

assay

97%

form

solid

bp

312 °C (lit.)

mp

103-107 °C (lit.)

density

0.88 g/mL at 25 °C (lit.)

SMILES string

C1c2ccccc2Cc3ccccc13

InChI

1S/C14H12/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-8H,9-10H2

InChI key

WPDAVTSOEQEGMS-UHFFFAOYSA-N

说明

General description

在 [7H] 苯并蒽催化剂存在下，9，10-二氢蒽可引起 C₆₀ 和 C₇₀ 的转移氢化。在作为氧化剂的分子氧和作为二甲苯中的促进剂的活性炭存在下，它被氧化芳构化为相应的蒽。

Application

9，10-二氢蒽（DHA）长期用于在研究中评估 MeCN 中价离域铁络合物的夺氢能力。

pictograms

GHS09

signalword

Warning

hcodes

H400

pcodes

P273

Hazard Classifications

Aquatic Acute 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.

Genqiang Xue et al.

Proceedings of the National Academy of Sciences of the United States of America, 104(52), 20713-20718 (2007-12-21)

Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [Fe(IV)(2)(mu-O)(2)] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been performed in

Oxidative aromatization of 9,10-dihydroanthracenes using molecular oxygen promoted by activated carbon.

Natsuki Nakamichi et al.

The Journal of organic chemistry, 68(21), 8272-8273 (2003-10-11)

Substituted 9,10-dihydroanthracenes were oxidatively aromatized to the corresponding anthracenes effectively by using molecular oxygen as an oxidant and activated carbon (Darco KB, Aldrich, Inc.) as a promoter in xylene.

[7H] Benzanthrone, a catalyst for the transfer hydrogenation of C₆₀and C₇₀by 9, 10-dihydroanthracene.

Gerst M, et al.

Tetrahedron Letters, 34(48), 7729-7732 (1993)

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全球贸易项目编号

货号	GTIN
126179-100G	04061833063422
126179-5G	04061838723895