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135194

溴代环己烷

Name: 溴代环己烷
Brand: ALDRICH

98%

别名:

环己基溴

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关于此项目

经验公式（希尔记法）:

C₆H₁₁Br

化学文摘社编号:

108-85-0

分子量:

163.06

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24848205

EC Number:

203-622-2

Beilstein/REAXYS Number:

1098373

MDL number:

MFCD00003819

Assay:

98%

Form:

liquid

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属性

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.495 (lit.)

bp

166-167 °C (lit.)

solubility

H₂O: insoluble, alcohol: soluble

density

1.324 g/mL at 25 °C (lit.)

functional group

bromo

SMILES string

BrC1CCCCC1

InChI

1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2

InChI key

AQNQQHJNRPDOQV-UHFFFAOYSA-N

说明

General description

溴代环己烷的轴向构象异构体与 9，9′-联蒽基形成包合物，并表现出弱的 1，3-二轴 Cl ... H 相互作用。以石墨作为催化剂，它可参与对-二甲苯的烷基化反应，生成烃。

Application

通过真空紫外质谱分析阈值电离光谱法，溴代环己烷可用于研究椅基溴环己烷的赤道和轴向构象异构体的电离。

Hazard Classifications

Aquatic Chronic 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Isolation of axial conformers of chloro- and bromocyclohexane in a pure state as inclusion complexes with 9,9'-bianthryl, and the discovery of a novel 1,3 diaxial Cl...H weak interaction.

Shinya Hirano et al.

Chemical communications (Cambridge, England), (29)(29), 3646-3648 (2005-07-20)

The axial conformers of chloro- and bromocyclohexane were isolated in a pure state as inclusion complexes with 9,9'-bianthryl, and a 1,3 diaxial Cl...H weak interaction was discovered by X-ray analysis of the axial conformer of chlorocyclohexane.

Conformer-specific ionization spectroscopy of bromocyclohexane: equatorial versus axial conformers.

Songhee Han et al.

The journal of physical chemistry. A, 114(37), 10005-10010 (2010-08-27)

Ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane is investigated with use of the vacuum ultraviolet mass-analyzed threshold ionization (MATI) spectroscopic technique. Two distinct ionization energies of 9.8308 ± 0.0025 and 9.8409 ± 0.0025 eV are determined for

Alkylation on graphite in the absence of Lewis acids.

Sereda GA.

Tetrahedron Letters, 45(39), 7265-7267 (2004)

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全球贸易项目编号

货号	GTIN
840435P-200MG	04061835228850
840435P-25MG	04061835228867
135194-100G	04061838345899
135194-1KG	04061838345905
135194-500G	04061838730558
135194-5G	04061838345912