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147982

(S)-(+)-2-辛醇

Name: (<I>S</I>)-(+)-2-辛醇
Brand: ALDRICH

99%

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关于此项目

线性分子式:

CH₃(CH₂)₅CH(OH)CH₃

化学文摘社编号:

6169-06-8

分子量:

130.23

UNSPSC Code:

12352001

NACRES:

NA.22

PubChem Substance ID:

24848871

EC Number:

228-213-6

Beilstein/REAXYS Number:

1719323

MDL number:

MFCD00064283

Assay:

99%

Form:

liquid

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属性

Quality Level

100

assay

99%

form

liquid

optical activity

[α]20/D +9.5°, neat

optical purity

ee: 98% (GLC)

refractive index

n20/D 1.426 (lit.)

bp

175 °C (lit.)

density

0.822 g/mL at 25 °C (lit.)

SMILES string

CCCCCC[C@H](C)O

InChI

1S/C8H18O/c1-3-4-5-6-7-8(2)9/h8-9H,3-7H2,1-2H3/t8-/m0/s1

InChI key

SJWFXCIHNDVPSH-QMMMGPOBSA-N

说明

Application

(S)-(+)-2-辛醇可被用于：

制备5-苄氧基异邻苯二甲酸衍生物溶液，其可被用作包含有热解石墨的2D手性自组装系统。
作为手性模板用于研究对映选择性乙二醇酯化。
作为起始材料用于制备(+)-(S)-2-甲苯磺酸辛酯，一种可用于制备(−)-(R)-2-卤代和叠氮辛烷的中间体。

pictograms

GHS07

signalword

Warning

hcodes

H319

pcodes

P264 - P280 - P305 + P351 + P338 - P337 + P313

Hazard Classifications

Eye Irrit. 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

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Convenient preparation of optically active 2-halooctanes and related compounds

San Filippo Jr J and Romano LJ

The Journal of Organic Chemistry, 40(10), 1514-1515 (1975)

Effect of imprinting sol-gel immobilized lipase with chiral template substrates in esterification of (R)-(+)-and (S)-(-)-glycidol.

Furukawa S, et al.

Journal of Molecular Catalysis. B, Enzymatic, 17(1), 23-28 (2002)

Highly efficient asymmetric reduction of 2-octanone in biphasic system by immobilized Acetobacter sp. CCTCC M209061 cells.

Xiao-Yang Ou et al.

Journal of biotechnology, 299, 37-43 (2019-05-03)

Highly efficient asymmetric reduction of 2-octanone to (R)-2-octanol catalyzed by immobilized Acetobacter sp. CCTCC M209061 cells was achieved in a biphasic system. Bioreduction conducted in aqueous single phase buffer was limited due to poor solubility and toxicity towards cells cause

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全球贸易项目编号

货号	GTIN
147982-5G	04061838737786