156671
叔丁醇钾
reagent grade, ≥98%
别名:
次丁氧基钾, 第三丁氧基钾
登录 查看组织和合同定价。
选择尺寸
变更视图
关于此项目
线性分子式:
(CH3)3COK
化学文摘社编号:
分子量:
112.21
UNSPSC Code:
12352303
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-740-3
Beilstein/REAXYS Number:
3556712
MDL number:
Assay:
≥98%
Grade:
reagent grade
Form:
solid
Solubility:
soluble, water: soluble (Hydrolysis, (rigorous decomposition))
grade
reagent grade
Quality Level
vapor pressure
1 mmHg ( 220 °C)
assay
≥98%
form
solid
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
256-258 °C (dec.) (lit.)
solubility
soluble, water: soluble (Hydrolysis, (rigorous decomposition))
greener alternative category
SMILES string
[K+].CC(C)(C)[O-]
InChI
1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChI key
LPNYRYFBWFDTMA-UHFFFAOYSA-N
General description
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处，查看更多详情。
Application
叔丁醇钾已作为强碱，用于通过N-叔丁基亚磺酰亚胺的转移氢化反应合成高对映体选择性的胺。
它也可用于：
它也可用于：
- 由酯和胺合成相应的脂肪和芳香酰胺。
- 在芳基醚、胺和酰胺的分子内环化中用作碱。
- 作为催化剂，通过芳基卤和烯烃的Mizoroki-Heck反应制备苯乙烯衍生物。
Still not finding the right product?
Explore all of our products under 叔丁醇钾
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 2 - Skin Corr. 1A
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
Mizoroki-Heck-type reaction mediated by potassium tert-butoxide
Shirakawa E, et al.
Angewandte Chemie (International ed. in English), 123(20), 4767-4770 (2011)
"Potassium tert-Butoxide Promoted Intramolecular Arylation via a Radical Pathway"
Roman SD, et al.
Organic Letters, 13(12), 3242-3245 (2011)
tert-Butoxide-assisted amidation of esters under green conditions
Kim Bo Ram, et al.
Synthesis, 44(01), 42-50 (2012)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 156671-25G | 04061838742858 |
| 156671-25KG | 04061833509173 |
| 156671-5G | 04061833410028 |
| 156671-100G | 04061838742834 |
| 156671-2.5KG | 04061838742841 |
| 156671-500G | 04061838742865 |