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175404

4-异丙基苯酚

Name: 4-异丙基苯酚
Brand: ALDRICH

98%

别名:

对枯烯醇

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关于此项目

线性分子式:

(CH₃)₂CHC₆H₄OH

化学文摘社编号:

99-89-8

分子量:

136.19

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850500

EC Number:

202-798-8

Beilstein/REAXYS Number:

1363564

MDL number:

MFCD00002372

Assay:

98%

Form:

crystals

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属性

vapor density

>1 (vs air)

Quality Level

100

assay

98%

form

crystals

bp

212-213 °C (lit.)

mp

59-61 °C (lit.)

SMILES string

CC(C)c1ccc(O)cc1

InChI

1S/C9H12O/c1-7(2)8-3-5-9(10)6-4-8/h3-7,10H,1-2H3

InChI key

YQUQWHNMBPIWGK-UHFFFAOYSA-N

说明

General description

对 4-异丙基苯酚的声化学降解进行了研究。

Application

乙烯基化合物的合成中使用了 4-异丙基苯酚。

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pictograms

GHS05,GHS07

signalword

Danger

hcodes

H302 + H312 + H332,H314

pcodes

P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

230.0 °F - Pensky-Martens closed cup

flash_point_c

110 °C - Pensky-Martens closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

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ipso-substitution: a general biochemical and biodegradation mechanism to cleave alpha-quaternary alkylphenols and bisphenol A.

Frédéric L P Gabriel et al.

Chemistry & biodiversity, 4(9), 2123-2137 (2007-09-25)

Sphingobium xenophagum Bayram is capable of metabolizing 4-alkoxyphenols and endocrine disruptive alpha-quaternary 4-nonylphenols by an ipso-substitution mechanism that involves ring hydroxylation at the site of the substituent. Here, we show that Bayram's ipso-hydroxylating activity was able to transform also bisphenol

Alkylphenol biotransformations catalyzed by 4-ethylphenol methylenehydroxylase.

David J Hopper et al.

Applied and environmental microbiology, 69(6), 3650-3652 (2003-06-06)

4-ethylphenol methylenehydroxylase from Pseudomonas putida JD1 acts by dehydrogenation of its substrate to give a quinone methide, which is then hydrated to an alcohol. It was shown to be active with a range of 4-alkylphenols as substrates. 4-n-propylphenol, 4-n-butylphenol, chavicol

Quinone methide formation from para isomers of methylphenol (cresol), ethylphenol, and isopropylphenol: relationship to toxicity.

D C Thompson et al.

Chemical research in toxicology, 8(1), 55-60 (1995-01-01)

The oxidative metabolism and toxicity of the para isomers of methylphenol (cresol), ethylphenol, and isopropylphenol were studied using male Sprague-Dawley rat liver microsomes and precision-cut liver slices. Reactive intermediates from each compound were trapped using radiolabeled glutathione and were detected

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全球贸易项目编号

货号	GTIN
175404-100G	04061838752253
175404-5G	04061838752260