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198005

2-氯-1-甲基吡啶碘化物

Name: 2-氯-1-甲基吡啶碘化物
Brand: ALDRICH

97%

别名:

Mukaiyama试剂

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关于此项目

经验公式（希尔记法）:

C₆H₇ClIN

化学文摘社编号:

14338-32-0

分子量:

255.48

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24851856

EC Number:

238-288-7

Beilstein/REAXYS Number:

3572320

MDL number:

MFCD00011984

Assay:

97%

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属性

Quality Level

200

assay

97%

mp

200 °C (dec.) (lit.)

functional group

chloro

SMILES string

[I-].C[n+]1ccccc1Cl

InChI

1S/C6H7ClN.HI/c1-8-5-3-2-4-6(8)7;/h2-5H,1H3;1H/q+1;/p-1

InChI key

ABFPKTQEQNICFT-UHFFFAOYSA-M

说明

General description

2-氯-1-甲基吡啶碘化物（Mukaiyama试剂）是有机合成中的常用试剂，用于活化醇的羟基和羧酸。它可用于以相应的羧酸合成酯、内酯、酰胺、内酰胺和烯酮的衍生物。由于其毒性低、反应条件简单、价格比EDC便宜，它还可用作肽合成中的高效偶联剂。

Application

2-氯-1-甲基吡啶碘化物（CMPI）可用作：

脱水剂，用于将各种醛肟转化为腈，醇转化为硫氰酸烷基酯。
交联剂，用于制备用于生物医学应用的可生物降解交联透明质酸膜和明胶膜。
缩合剂，用于以β氨基酸合成各种β内酰胺。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

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全球贸易项目编号

货号	GTIN
487031-5G	04061833366325
198005-100G	04061838346964
198005-10G	04061838762627
198005-25G	04061838762634