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208523

三氯化钌

Anhydrous, solid, Ru content 45-55%

别名:

Ruthenium trichloride

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关于此项目

线性分子式:
RuCl3
化学文摘社编号:
10049-08-8
分子量:
207.43
NACRES:
NA.22
PubChem Substance ID:
24852520
UNSPSC Code:
12161600
EC Number:
233-167-5
MDL number:
MFCD00011208
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产品名称

三氯化钌, Anhydrous, solid, Ru content 45-55%

Quality Level

200

form

solid

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

density

3.11 g/mL at 25 °C (lit.)

SMILES string

Cl[Ru](Cl)Cl

InChI

1S/3ClH.Ru/h3*1H;/q;;;+3/p-3

InChI key

YBCAZPLXEGKKFM-UHFFFAOYSA-K

General description

氯化钌（III）是一种化合物，它可用作温和的路易斯酸催化剂，用于醛的缩醛化、醇的缩醛化和酮肟向酰胺的转化。 此外，它也可作为前体用于合成钌纳米颗粒。

Application

氯化钌（III）可用作以下反应的催化剂：：

  • 通过环氧化物与苯胺的亲核开环反应合成β‐氨基醇。
  • 在温和条件下各种酚、醇、硫醇和胺的乙酰化反应。
  • 通过混合醛、胺和三甲基氰硅烷合成α‐氨基腈。

Other Notes

不溶物形式

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCQ9411
MKCQ9412
MKCQ1043
MKCM5968
MKCM5969

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实验方案

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

商品

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Isabel Serrano et al.
Inorganic chemistry, 45(6), 2644-2651 (2006-03-15)
The synthesis of two Ru chloro complexes, Ru(III)Cl(3)(bpea), 1, and cis-fac-Delta-[Ru(II)Cl{(R)-(bpea)}{(S)-(BINAP)}](BF(4)), cis-fac-Delta-(R)-(S)-2, (bpea = N,N-bis(2-pyridylmethyl)ethylamine; (S)-BINAP = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl), is described. Complex 2 is characterized in solution through UV-vis, cyclic voltammetry (CV), and 1D and 2D NMR spectroscopy. X-ray diffraction analysis
Patrik Västilä et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(12), 3218-3225 (2006-01-28)
We studied the role of alkali cations in the [{RuCl2(p-cymene)}2]-pseudo-dipeptide-catalyzed enantioselective transfer hydrogenation of ketones with isopropanol. Lithium salts were shown to increase the enantioselectivity of the reaction when iPrONa or iPrOK was used as the base. Similar transfer-hydrogenation systems
Tetrahedron Letters, 48, 5131-5131 (2007)
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全球贸易项目编号

货号GTIN
208523-10G04061838769893
208523-2G04061838769909
208523-50G04061833545171