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关于此项目
经验公式(希尔记法):
CuI
化学文摘社编号:
分子量:
190.45
PubChem Substance ID:
eCl@ss:
38150105
UNSPSC Code:
12352302
NACRES:
NA.23
EC Number:
231-674-6
MDL number:
Assay:
99.999% trace metals basis
Form:
powder and chunks
Solubility:
dilute aqueous acid: insoluble(lit.)
vapor pressure
10 mmHg ( 656 °C)
Quality Level
assay
99.999% trace metals basis
form
powder and chunks
reaction suitability
core: copper
impurities
≤15.0 ppm Trace Metal Analysis
bp
1290 °C/1 atm (decomp)(lit.)
mp
605 °C (lit.)
solubility
dilute aqueous acid: insoluble(lit.)
density
5.62 g/mL at 25 °C (lit.)
SMILES string
[Cu+].[I-]
InChI
1S/Cu.HI/h;1H/q+1;/p-1
InChI key
LSXDOTMGLUJQCM-UHFFFAOYSA-M
Application
碘化亚铜可作为催化剂用于:
- 在温和、无配体条件下,通过偶联芳香重氮类化合物,芳基化吡唑及衍生物。
- 通过二溴烯烃与杂亲核试剂的选择性交叉偶联反应,形成各种合成砌块,例如1-溴烯酰胺、炔酰胺、烯酮N,N-缩醛、1-溴烯醇醚、炔醇醚、烯酮O,O-缩醛、乙烯基膦酸酯。
- 环硅丙烷和羰基化合物的立体特异性和区域选择性反应。
Features and Benefits
- 低毒
- 反应条件温和
- 高纯度保证重现性,防止污染物造成的共催化。
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Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
target_organs
Thyroid
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synlett, 1836-1836 (2007)
Synlett, 1917-1917 (2007)
Shangjun Cai et al.
The Journal of organic chemistry, 77(5), 2331-2336 (2012-02-04)
An efficient strategy for the synthesis of a variety of 3-substituted isocoumarins has been developed. The reaction proceeded from o-halobenzoic acids and 1,3-diketones via a copper(I)-catalyzed domino reaction in DMF under the action of K(3)PO(4) at 90-120 °C without a
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 215554-25G | 04061838773807 |
| 215554-100G | 04061838138378 |
| 215554-1KG | 04061826680216 |
| 215554-5G | 04061838773814 |



