Quality Level
assay
98%
form
solid
bp
171-172 °C/739 mmHg (lit.)
mp
40-43 °C (lit.)
solubility
alcohol: freely soluble, diethyl ether: freely soluble, hot water: freely soluble
functional group
hydroxyl
SMILES string
CC(C)(O)C(C)(C)O
InChI
1S/C6H14O2/c1-5(2,7)6(3,4)8/h7-8H,1-4H3
InChI key
IVDFJHOHABJVEH-UHFFFAOYSA-N
General description
已有研究报道了以无机电子 [Ca2N](+)·e(−)作为有机溶剂中的电子供体,与角叉菜胶发生频哪醇偶联反应。
Application
频哪醇是一种1,2-二醇,可用于:
- 作为一种配体,通过与硝酸铀酰和醋酸盐水合物的反应来制备铀酰复合物。
- 使用典型的频哪醇重排反应制备频哪酮和2,3-二甲基-1,3-丁二烯。
- 作为反应剂,合成4-(4,4,5,5-四甲基-1,3,2-二噁硼烷-2-乙基)苯甲酸,用于制备4-乙酸基-3-苯基苯甲醛衍生物。
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存储类别
11 - Combustible Solids
flash_point_f
170.6 °F - closed cup
flash_point_c
77 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Uranyl complexes with 1, 2-diols and tetrahydrofurfuryl alcohols
Villiers C, et al.
Polyhedron, 46(1), 133-138 (2012)
Fe-substituted molecular sieves as catalysts in liquid phase pinacol rearrangement
Hsien M, et al.
J. Mol. Catal. A: Chem., 181(1-2), 189-200 (2002)
Ye Ji Kim et al.
Chemical communications (Cambridge, England), 50(37), 4791-4794 (2014-04-02)
The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor in organic solvents. The bond cleavages of the [Ca2N](+) layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 221171-100G | 04061838777003 |
| 221171-250MG | 04061832879956 |
| 221171-500G | 04061838777010 |
| 221171-5G | 04061838777027 |