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Merck
CN

236330

对甲苯磺酰胺

ReagentPlus®, ≥99%

别名:

4-Methylbenzene-1-sulfonamide, p-Tosylamide

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关于此项目

线性分子式:
CH3C6H4SO2NH2
化学文摘社编号:
分子量:
171.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-741-1
Beilstein/REAXYS Number:
472689
MDL number:
Assay:
≥99%
Form:
solid
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Quality Level

product line

ReagentPlus®

assay

≥99%

form

solid

mp

134-137 °C (lit.)

SMILES string

Cc1ccc(cc1)S(N)(=O)=O

InChI

1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)

InChI key

LMYRWZFENFIFIT-UHFFFAOYSA-N

Gene Information

General description

研究了氰甲基三丁基磷 (CMBP) 介导的 甲苯磺酰胺与醇的反应 。

Application

p -甲苯磺酰胺已被用作:
  • 四丁基氟化铵 (TBAF) 催化乙烯基氮丙啶开环反应中的亲核试剂
  • 己内酰胺二铑 (II) 催化烯烃氮杂环丙烷化反应的试剂

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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存储类别

11 - Combustible Solids

flash_point_f

395.6 °F - closed cup

flash_point_c

202 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Mitsunobu-type alkylation of p-toluenesulfonamide. A convenient new route to primary and secondary amines.
Tsunoda T, et al.
Tetrahedron Letters, 37(!4), 2457-2458 (1996)
E Simone et al.
Lab on a chip, 18(15), 2235-2245 (2018-06-28)
In this work, a novel multi-microfluidic crystallization platform called MMicroCryGen is presented, offering a facile methodology for generating individual crystals for fast and easy screening of the polymorphism and crystal habit of solid compounds. The MMicroCryGen device is capable of
Arthur J Catino et al.
Organic letters, 7(13), 2787-2790 (2005-06-17)
[reaction: see text] A mild, efficient, and selective aziridination of olefins catalyzed by dirhodium(II) caprolactamate [Rh(2)(cap)(4).2CH(3)CN] is described. Use of p-toluenesulfonamide (TsNH(2)), N-bromosuccinimide (NBS), and potassium carbonate readily affords aziridines in isolated yields of up to 95% under extremely mild



全球贸易项目编号

货号GTIN
236330-10G04061838785572
236330-50G04061838785589