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Merck
CN

241059

溴化四乙铵

99%, crystals, suitable for for general lab use, ReagentPlus®

别名:

TEAB, 四乙溴铵

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关于此项目

线性分子式:
(C2H5)4N(Br)
化学文摘社编号:
分子量:
210.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352107
EC Number:
200-769-4
MDL number:
Beilstein/REAXYS Number:
3563430
Assay:
99%
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产品名称

溴化四乙铵, ReagentPlus®, 99%

Quality Level

product line

ReagentPlus®

assay

99%

form

crystals

reaction suitability

core: ammonium

dilution

(for general lab use)

impurities

1% triethylamine hydrobromide

pH

6.5 (100 g/L)

mp

285 °C (dec.) (lit.)

SMILES string

[Br-].CC[N+](CC)(CC)CC

InChI

1S/C8H20N.BrH/c1-5-9(6-2,7-3)8-4;/h5-8H2,1-4H3;1H/q+1;/p-1

InChI key

HWCKGOZZJDHMNC-UHFFFAOYSA-M

Application

  • 四乙基溴化铵(TEAB)可以催化醛或醇与硫醇或二硫化物的氧化偶联反应,合成硫酯。
  • 它与碘酰基苯甲酸(IBX)一起用作催化剂,将硫化物氧化成亚砜并将伯酰胺氧化成单碳dehomologated腈。
  • TEAB也可用作合成沸石β的有机模板。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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hcodes

Hazard Classifications

Aquatic Chronic 3

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

361.4 °F - closed cup

flash_point_c

183 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tetraethylammonium Bromide-Catalyzed Oxidative Thioesterification of Aldehydes and Alcohols.
Zhu, Xuebin et al.
advanced synthesis and catalysis, 355(18), 3558-3562 (2013)
Masoumeh Taherimehr et al.
ChemSusChem, 10(6), 1283-1291 (2016-12-20)
Metal-organic frameworks (MOFs) with accessible Lewis acid sites are finding increasing application in the field of heterogeneous catalysis. However, the structural instability of MOFs when they are exposed to high temperature and/or high pressure often limits their applicability. In this
Hydrothermal crystallization of zeolite beta using tetraethylammonium bromide.
Eapen M
Zeolites, 14(4), 295-302 (1994)



全球贸易项目编号

货号GTIN
241059-250G04061824485967
241059-50G04061824485974