277304
双(三甲基硅基)酰胺钾 溶液
0.5 M in toluene
别名:
六甲基二硅基胺基钾 溶液, 六甲基二硅氮烷 钾盐 溶液
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线性分子式:
[(CH3)3Si]2NK
化学文摘社编号:
分子量:
199.48
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4006754
Concentration:
0.5 M in toluene
Form:
liquid
vapor density
3.2 (vs air)
Quality Level
vapor pressure
54 mmHg ( 25 °C)
form
liquid
concentration
0.5 M in toluene
color
clear to slightly hazy yellow
density
0.877 g/mL at 25 °C
SMILES string
C[Si](C)(C)N([K])[Si](C)(C)C
InChI
1S/C6H18NSi2.K/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
IUBQJLUDMLPAGT-UHFFFAOYSA-N
Application
强碱，用于羰基化合物的烷基化。
Packaging
建议将25 mL Sure/Seal™ 瓶作为一次性瓶使用。反复穿刺可能会导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
44.6 °F - closed cup
flash_point_c
7 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
易制毒化学品（3类）
此项目有
Alan C Spivey et al.
Organic letters, 9(5), 891-894 (2007-02-10)
[reaction: see text] The scope and limitations of the conjugate addition of 2- and the first 4-pyridyl Gilman homocuprates to various alpha,beta-unsaturated Michael acceptors are delineated. The conjugate addition of the cuprate of 2-bromo-3-methylpyridine to (E)-methyl crotonate then diastereoselective enolate
Tatsuya Nitabaru et al.
Journal of the American Chemical Society, 131(38), 13860-13869 (2009-09-10)
Full details of an anti-selective catalytic asymmetric nitroaldol reaction promoted by a heterobimetallic catalyst comprised of Nd(5)O(O(i)Pr)(13), an amide-based ligand, and NaHMDS (sodium hexamethyldisilazide) are described. A systematic synthesis and evaluation of amide-based ligands led to the identification of optimum
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 277304-4X25ML | 04061826193389 |
| 277304-800ML | 04061826193396 |
| 277304-100ML | 04061826193372 |
| 277304-2L | 04061837670763 |