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Merck
CN

287822

三(邻甲基苯基)膦

97%

别名:

P(o-tol)3, 三(2-甲苯基)膦

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关于此项目

线性分子式:
(CH3C6H4)3P
化学文摘社编号:
分子量:
304.37
UNSPSC Code:
12352128
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-193-9
Beilstein/REAXYS Number:
661212
MDL number:
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Quality Level

assay

97%

reaction suitability

reaction type: Cross Couplings, reaction type: Silylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

123-125 °C (lit.)

functional group

phosphine

SMILES string

Cc1ccccc1P(c2ccccc2C)c3ccccc3C

InChI

1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3

InChI key

COIOYMYWGDAQPM-UHFFFAOYSA-N

General description

三(对甲苯基)膦是一种配体,用于丙烷基碳酸酯的heck反应和suzuki 偶联。

Application

用于钌催化下醇直接胺化的配体。


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存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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相关内容

Catalexis平台通过数字化优化催化剂筛选,识别出交叉偶联反应最有效的膦配体,从而增强催化作用。

The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.

Phosphine Ligand Application Guide


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Hybrid nanostructures with switchable and reversible "blue-red-green" emission were efficiently synthesized. These nanostructures comprise polyhedral oligomeric silsesquioxanes (POSS) that behave as a nanocage that can be functionalized with terpyridine-based organic ligands, which can be easily complexed with europium (III) ions.



全球贸易项目编号

货号GTIN
287822-10G04061826273234
287822-1G04061826273241