328103
3′-羟基苯乙酮
≥99%
别名:
1-(3-Hydroxyphenyl)ethanone, 3-Acetylphenol, 3-Hydroxyphenylethanone, m-Hydroxyacetophenone
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关于此项目
线性分子式:
HOC6H4COCH3
化学文摘社编号:
分子量:
136.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-494-0
Beilstein/REAXYS Number:
2040676
MDL number:
Assay:
≥99%
Quality Level
assay
≥99%
bp
296 °C (lit.)
mp
90-95 °C (lit.)
density
1.1 g/mL at 25 °C (lit.)
functional group
ketone
SMILES string
CC(=O)c1cccc(O)c1
InChI
1S/C8H8O2/c1-6(9)7-3-2-4-8(10)5-7/h2-5,10H,1H3
InChI key
LUJMEECXHPYQOF-UHFFFAOYSA-N
General description
3′-Hydroxyacetophenone is an hydroxy-substituted alkyl phenyl ketone.
Application
3′-Hydroxyacetophenone was used in synthesis of enantiopure (-)-rivastigmine. It was also used in preparation of building block for synthesis of dendritic compounds.
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
247.3 °F - closed cup
flash_point_c
119.6 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis of polyester dendrimers and dendrons starting from Michael reaction of acrylates with 3-hydroxyacetophenone.
Hirayama Y, et a
Tetrahedron Letters, 46(6), 1027-1030 (2005)
Katharine Moore Tibbetts et al.
The journal of physical chemistry. A, 118(37), 8170-8176 (2014-03-01)
The hydroxy-substituted alkyl phenyl ketones 2'-, 3'- and 4'- (ortho, meta, and para) hydroxyacetophenone were excited in the strong-field regime with wavelengths ranging from 1200-1500 nm to produce the respective radical cations. For 2'- and 3'-hydroxyacetophenone, the parent molecular ion
Kiwon Han et al.
The Journal of organic chemistry, 75(9), 3105-3108 (2010-03-30)
A practical and efficient procedure for the synthesis of rivastigmine was developed. This procedure includes dynamic kinetic resolution using a polymer-bound ruthenium complex and a lipase in combination as a key step. Enantiopure (-)-rivastigmine was obtained from commercially available 3'-hydroxyacetophenone
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 328103-5G | 04061826717219 |
| 328103-25G | 04061826717202 |