产品名称
氯化锰, flakes, 98%
Quality Level
assay
98%
form
flakes
reaction suitability
core: manganese, reagent type: catalyst
mp
652 °C (lit.)
density
2.98 g/mL at 25 °C (lit.)
SMILES string
Cl[Mn]Cl
InChI
1S/2ClH.Mn/h2*1H;/q;;+2/p-2
InChI key
GLFNIEUTAYBVOC-UHFFFAOYSA-L
Application
通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构，在基态时具有 24 个不成对电子。还用于形成可用于自由基环化反应的活性 Mn(0) 物质。
制备有机氯化锰试剂的起始物料；还原乙烯基和芳基卤化物，乙烯基碘的立体选择性偶联和烯醇三氟甲磺酸酯的烷基化的催化剂；也用于 Mn-Cu 催化的 RMgX 与烯酮的共轭加成和用酰氯的 Mn 催化酰化 RMgX；与 NaBH4 组合是非对映选择性还原剂；用于选择性地、立体地制备烯醇化锰的起始物料。
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2
target_organs
Brain
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
Jerome A Roth et al.
Toxicology in vitro : an international journal published in association with BIBRA, 26(7), 1143-1149 (2012-07-31)
Mutations in the parkin gene are linked to development of juvenile onset of Parkinson's disease and recent studies have reported that parkin can protect against increased oxidative stress and mitochondrial dysfunction caused by a variety of oxidative and toxic insults.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 328146-25G | 04061826717271 |
| 328146-2KG | 04061826717288 |
| 328146-500G | 04061826717295 |