二氯(p-甲基异丙苯)钌(II) 二聚体
≥95%, powder
别名:
(对伞花烃)钌二氯二聚体, 苯，1-甲基-4-(1-甲基乙基)- ，钌络合物
登录 查看组织和合同定价。
选择尺寸
变更视图
关于此项目
线性分子式:
[Ru(p-cymene)Cl2]2
化学文摘社编号:
分子量:
612.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
assay
≥95%
form
powder
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
247.0-250.0 °C (dec.) (lit.)
greener alternative category
, Aligned
SMILES string
Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2
InChI
1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
LAXRNWSASWOFOT-UHFFFAOYSA-J
General description
我们竭诚为您提供绿色替代产品，以确保符合一项或多项绿色化学12项原则要求。该产品为增强型，提高了催化效率。点击此处了解更多信息。
二碘(对伞花烃)钌(II)二聚体是一种饱和的18电子络合物，可用作合成有机金属络合物的起始原料。
二碘(对伞花烃)钌(II)二聚体是一种饱和的18电子络合物，可用作合成有机金属络合物的起始原料。
Application
环金属化钌与芳基亚胺和含氮杂环通过C-H键活化发生络合反应
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
Carina Sollert et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(14), 5380-5386 (2015-02-18)
The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including bromides and
Bin Li et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 343706-1G | 04061826758328 |
| 343706-5G | 04061826758359 |