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关于此项目
线性分子式:
NaOC(CH3)3
化学文摘社编号:
分子量:
96.10
UNSPSC Code:
12352107
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-741-9
Beilstein/REAXYS Number:
3654215
MDL number:
Assay:
97%
Form:
powder, crystals or chunks
vapor pressure
0.0000026 hPa ( 50 °C)
assay
97%
form
powder, crystals or chunks
density
1,025 g/cm3 at 20 °C
SMILES string
[Na+].CC(C)(C)[O-]
InChI
1S/C4H9O.Na/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChI key
MFRIHAYPQRLWNB-UHFFFAOYSA-N
Application
叔丁醇钠可用作安全有效的氢化钠替代物，用于羟乙基腺嘌呤和二乙基p-对甲苯磺酰氧基甲基膦酸酯偶合生成9-[2-(二乙基磷酰甲氧基)乙烷]腺嘌呤(二乙基-PMEA), 这是制备阿德福韦酯的重要中间体。
它还可以用于：
它还可以用于：
- 在10-菲咯啉衍生物存在下，辅助卤代芳烃与苯衍生物偶合反应。
- 可以激活第一副族过渡金属预催化剂。
- 在一种新型环钯化预催化剂存在下，是芳基氯化物氨基化的一种碱。
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
57.2 °F
flash_point_c
14 °C
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Process optimization in the synthesis of 9-[2-(diethylphosphonomethoxy) ethyl] adenine: replacement of sodium hydride with sodium tert-butoxide as the base for oxygen alkylation.
Yu RH, et al.
Organic Process Research & Development, 3(1), 53-55 (1999)
Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxide.
Docherty JH, et al.
Nature Chemistry, 9(6), 595-595 (2017)
tert-Butoxide-mediated arylation of benzene with aryl halides in the presence of a catalytic 1, 10-phenanthroline derivative.
Shirakawa E, et al.
Journal of the American Chemical Society, 132(44), 15537-15539 (2010)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 359270-100G | 04061831813166 |
| 359270-500G | 04061831813180 |
| 359270-25G | 04061831813173 |
| 359270-5G | 04061831813197 |
| 359270-1.5KG | 04061831813159 |