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372870

氯化亚铁

Name: 氯化亚铁
Brand: ALDRICH

98%, powder

别名:

二氯化铁, 氯化亚铁

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关于此项目

线性分子式:

FeCl₂

化学文摘社编号:

7758-94-3

分子量:

126.75

NACRES:

NA.22

PubChem Substance ID:

24863176

UNSPSC Code:

12161600

EC Number:

231-843-4

MDL number:

MFCD00011004

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属性

产品名称

氯化亚铁, 98%

Quality Level

100

assay

98%

form

powder

reaction suitability

core: iron, reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

677 °C (lit.)

density

3.16 g/mL at 25 °C (lit.)

greener alternative category

, Aligned

SMILES string

Cl[Fe]Cl

InChI

1S/2ClH.Fe/h2*1H;/q;;+2/p-2

InChI key

NMCUIPGRVMDVDB-UHFFFAOYSA-L

说明

General description

我们致力于为您提供更环保的替代产品，以符合“绿色化学的 12 项原则”的一项或多项原则要求。这种铁催化剂价格便宜且对环境友好。点击此处了解更多信息。

Application

氯化铁可用于催化：

格里纳德氏化合物的制备，如1-萘基氯化镁。
在丙酮肟存在下，将2,4,6-三甲基苯酚（2,4,6-TMP）选择性氧化生成3,5-二甲基-4-羟基苯甲醛（DMHB）。
用FeCl₂ 改性的Raney型催化剂可以催化α,β-不饱和醛的增强选择性氢化反应生成不饱和醇。

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pictograms

GHS05,GHS07

signalword

Danger

hcodes

H302,H318

pcodes

P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P501

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

does not flash

flash_point_c

does not flash

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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实验方案

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

商品

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Liquid-phase Selective Hydrogenation of an Aliphatic ?, ?-Unsaturated Aldehyde over Raney Cobalt Catalyst Modified with Ferrous Chloride.

Hotta K, et al.

Bulletin of the Chemical Society of Japan, 42(5), 1447-1449 (1969)

2, 4, 6-Trimethylphenol oxidation with ferrous chloride catalyst: Effect of acetoxime addition.

Li K, et al.

J. Mol. Catal. A: Chem., 241(1-2), 72-78 (2005)

Transition metal catalyzed preparation of Grignard compounds.

Bogdanovic B, et al.

Angewandte Chemie (International Edition in English), 39(24), 4610-4612 (2000)

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全球贸易项目编号

货号	GTIN
372870-250G	04061831834314
372870-25G	04061838253538