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Merck
CN

454338

二聚环戊二烯

contains BHT as stabilizer

别名:

4,7-亚甲基-3a,4,7,7a-四氢茚, DCPD, 环戊二烯二聚体

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关于此项目

经验公式(希尔记法):
C10H12
化学文摘社编号:
分子量:
132.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-052-9
MDL number:
Beilstein/REAXYS Number:
1904092
Assay:
≥96.0%
Form:
liquid
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assay

≥96.0%

Quality Level

form

liquid

contains

BHT as stabilizer

bp

170 °C ((lit.)), 170 °C (lit.)

mp

33 °C ((lit.)), 33 °C (lit.)

solubility

water: slightly soluble 0.02 g/L at 25 °C

density

0.986 g/mL at 25 °C ((lit.)), 0.986 g/mL at 25 °C (lit.)

SMILES string

C1C=CC2C3CC(C=C3)C12

InChI

[1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7-,8+,9?,10?/m0/s1], 1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7-,8+,9?,10?/m0/s1

InChI key

[HECLRDQVFMWTQS-AFWXGSBKSA-N], HECLRDQVFMWTQS-AFWXGSBKSA-N

General description

双环戊二烯(DCPD)是环戊二烯的二聚体,由两个不饱和双键组成(一个在降冰片烯环上,一个在环戊烯环上)。DCPT 可单独用于聚合物中,也可与其他碳氢化合物一起使用。它也用于制药、弹性体、聚碳酸酯和聚酯树脂。

Application

双环戊二烯可用于:
  • 采用 VARTM(真空辅助树脂转移模塑)工艺制备 CF/p-DCPD(碳纤维/聚双环戊二烯)复合材料。
  • 在 η5-环戊二烯基三(二甲基氨基)锆催化剂的制备中。
  • 在纤维素–马来酸酐–双环戊二烯共聚物基体的自由基聚合合成中。

Features and Benefits

DCPD 与邻苯二甲酸和间苯二甲酸聚酯相比具有以下优点:
  • 低收缩率
  • 降低成本效益
  • 减少苯乙烯的排放
  • 薄层快速固化


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signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

89.6 °F - closed cup

flash_point_c

32 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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Anna Kozłowska et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 20(43), 14120-14125 (2014-09-11)
Cyclic Ru-phenolates were synthesized, and these compounds were used as olefin metathesis catalysts. Investigation of their catalytic activity pointed out that, after activation with chemical agents, these catalysts promote ring-closing metathesis (RCM), enyne and cross-metathesis (CM) reactions, including butenolysis, with
Morphological and mechanical evaluation of hybrid organic-inorganic thermoset copolymers of dicyclopentadiene and mono-or tris (norbornenyl)-substituted polyhedral oligomeric silsesquioxanes.
Constable GS, et al.
Macromolecules, 37(4), 1276-1282 (2004)
Sebastijan Kovačič et al.
ACS applied materials & interfaces, 6(21), 19075-19081 (2014-10-22)
Zinc(II) oxide nanoparticles were used for the stabilization of dicyclopentadiene (DCPD)-water-based high internal phase emulsions (HIPEs), which were subsequently cured using ring-opening metathesis polymerization (ROMP). The morphology of the resulting ZnO-pDCPD nanocomposite foams was investigated in correlation to the nanoparticle



全球贸易项目编号

货号GTIN
454338-100G04061832340425
454338-2.5KG04061832340432
454338-1KG04061837323928
454338-500G04061832340449