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456055

莰烯

Name: 莰烯
Brand: ALDRICH

95%

别名:

(±)-莰烯, 2,2-二甲基-3-亚甲基双环[2.2.1]庚烷, 2,2-二甲基-3-亚甲基降冰片烷, 2,2-二甲基-3-甲亚基双环[2.2.1]庚烷, 2-亚甲基-3,3-二甲基双环[2.2.1]庚烷, 3,3-二甲基-2-亚甲基降冰片烷, 3,3-二甲基-2-亚甲基降莰烷, DL-莰烯

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₆

化学文摘社编号:

79-92-5

分子量:

136.23

NACRES:

NA.22

PubChem Substance ID:

24869106

UNSPSC Code:

12352100

EC Number:

201-234-8

MDL number:

MFCD00066603

Assay:

95%

Form:

solid

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属性

Quality Level

100

assay

95%

form

solid

bp

159-160 °C (lit.)

mp

48-52 °C (lit.)

density

0.85 g/mL at 25 °C (lit.)

SMILES string

[H][C@]12CC[C@]([H])(C1)C(C)(C)C2=C

InChI

1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9+/m0/s1

InChI key

CRPUJAZIXJMDBK-DTWKUNHWSA-N

说明

General description

莰烯是双环单萜，是多种植物精油中的成分，包括月桃(Alpinia speciosa)、苍耳(Xanthium strumarium)叶、山松Pinus uncinata和Pinus uliginosa的松针。(5)

Application

莰烯作为反应剂的用途如下：

通过二氧化硅负载磷钨酸催化的C₂-C₆脂肪酸液相酯化反应合成异冰片基羧酸酯。
过氧化双月桂酰为引发剂，与N-羟基邻苯二甲酰亚胺和亚磷酸三乙酯通过分子间反马氏(anti-Markovnikov)氢胺化反应合成氢胺化莰烯。
H₂O₂为氧化剂，吡唑为路易斯碱加合物，通过甲基三氧化铼催化的环氧化反应合成莰烯氧化物。
与醇通过阳离子交换树脂催化的烷氧化反应合成异冰片基烷醚。

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pictograms

GHS02,GHS07,GHS09

signalword

Danger

hcodes

H228,H319,H410

pcodes

P210 - P240 - P241 - P264 - P273 - P305 + P351 + P338

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Sol. 1

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 2

flash_point_f

78.8 °F - DIN 51755 Part 1

flash_point_c

26 °C - DIN 51755 Part 1

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

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实验方案

GC Analysis of Sweet Orange Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 µm), Fast GC Analysis

-β-Farnesene; α-Huµlene; Germacrene D; (+)-Valencene; Bicyclogermacrene; (+)-δ-Cadinene

Dendritic growth kinetics and structure II. Camphene.

Rubinstein ER and Glicksman ME.

Journal of Crystal Growth, 112(1), 97-110 (1991)

Phytochemical compositions and biological activities of essential oil from Xanthium strumarium L.

Javad Sharifi-Rad et al.

Molecules (Basel, Switzerland), 20(4), 7034-7047 (2015-04-22)

The chemical composition of the essential oil (EO) from fresh cocklebur (Xanthium strumarium L.) leaves was investigated by GC-MS. The antimicrobial activity of the EO was tested against Gram-positive and Gram-negative bacteria and fungi. Scolicidal activity was assayed against Echinococcus

Composition of essential oils isolated from the needles of Pinus uncinata and P. uliginosa grown in Poland.

Radosław Bonikowski et al.

Natural product communications, 10(2), 371-373 (2015-04-30)

The compositions of mountain pine (Pinus uncinata) and peat-bog pine (P. uliginosa) needle essential oils were investigated. Enantiomeric compositions of selected monoterpene hydrocarbons were also examined. Respectively, fifty-three and seventy-six components of the essential oils were identified using GC-MS and

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全球贸易项目编号

货号	GTIN
456055-1KG	04061832341125
456055-25G	04061832341132