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关于此项目
线性分子式:
HCOCH2NHCO2C(CH3)3
化学文摘社编号:
分子量:
159.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Quality Level
assay
95%
refractive index
n20/D 1.455 (lit.)
functional group
aldehyde, amine
storage temp.
−20°C
SMILES string
CC(C)(C)OC(=O)NCC=O
InChI
1S/C7H13NO3/c1-7(2,3)11-6(10)8-4-5-9/h5H,4H2,1-3H3,(H,8,10)
InChI key
ACNRTYKOPZDRCO-UHFFFAOYSA-N
Gene Information
human ... CTSK(1513)
General description
N -Boc-2-氨基乙醛是一种有机构件。与 Horner-Wadsworth-Emmons (HWE) 试剂反应,得到 γ-氨基丁酸 (GABA) 衍生的 α-酮酰胺/酯单元。
Application
使用最近报道的涉及甲醛和吡咯烷丙酸或二肽 L-Pro-β-Ala 催化的方案,该氨基醛的 α-亚甲基化以快速有效的方式进行。
也用于含 1,3-偶极环加成的吡咯烷的三组分合成。
也用于含 1,3-偶极环加成的吡咯烷的三组分合成。
N -Boc-2-氨基乙醛可用于以下用途:
- 作为 (+)-负霉素全合成中的起始试剂。
- ( E )-4-(( 叔 -丁氧基羰基)氨基)-2-烯酸乙酯的合成。
- 2,2′ 的合成-联吡啶。
受保护的吡咯脯氨酸合成中的一个组成部分。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
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全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 472654-25G | 04061833490358 |
| 472654-1G | 04061825585482 |
| 472654-5G | 04061832360683 |