grade
reagent grade
assay
95%
expl. lim.
8 % (lit.)
impurities
≤0.20% water
water
refractive index
n20/D 1.419 (lit.)
bp
71-72 °C/11 mmHg (lit.)
mp
-38 °C (lit.)
density
0.954 g/mL at 25 °C (lit.)
functional group
ester, ketone
SMILES string
CC(=O)CC(=O)OC(C)(C)C
InChI
1S/C8H14O3/c1-6(9)5-7(10)11-8(2,3)4/h5H2,1-4H3
InChI key
JKUYRAMKJLMYLO-UHFFFAOYSA-N
General description
叔 -乙酰乙酸叔丁酯 ( t -BAA) 是一种廉价且易于储存的商品试剂。反应证明更妨碍的乙酰乙酸叔丁酯 (t-BAA，la) 比更常用的甲基或乙基类似物活性高 15-20 倍。其广泛用作乙酰化试剂。
Application
叔-丁基乙酰乙酸盐可用于合成：
- 各种乙酰乙酸衍生物
- 乙酰乙酸盐类
- 乙酰乙酰胺
- 1-（二乙氨基）-2-乙酰乙酰氧基丙烷
- ( S )- 叔 -3-羟基丁酸丁酯
- 苯并噻唑 β-酮酯衍生物
- 3,4-双取代吡咯
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存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
150.8 °F - closed cup
flash_point_c
66 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of (S)-Tert-Butyl 3-Hydroxybutyrate by Asymmetric Reduction of Tert-Butyl Acetoacetate with Saccharomyces cerevisiae B5.
Ou ZM, et al.
Advanced Materials Research, 704 (2013)
Enzymatic Synergism in the Synthesis of ?-Keto Esters.
Wisniewska C, et al.
European Journal of Organic Chemistry, 24, 5432-5437 (2015)
Highly enantioselective Mannich reactions of imines with tert-butyl acetoacetate catalyzed by squaramide organocatalyst.
He HX and Du DM.
Tetrahedron Asymmetry, 25(8), 637-643 (2014)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 537594-1L | 04061836692841 |
| 537594-500ML | 04061832565811 |
| 537594-100ML | 04061832565798 |
| 537594-4L | 04061832565804 |