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677280

sSPhos

solid

别名:

2′-二环己基膦基-2,6-二甲氧基-1,1′-联苯基-3-磺酸钠 水合物, SPhos（水溶性）, [1,1′-2′-联苯基 ]-3-磺酸-（二环己基膦）-2,6-二甲氧基钠盐

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关于此项目

经验公式（希尔记法）:
C26H34NaO5PS · xH2O
化学文摘社编号:
1049726-96-6
分子量:
512.57 (anhydrous basis)
UNSPSC Code:
12352103
PubChem Substance ID:
24885361
NACRES:
NA.22
MDL number:
MFCD07781994
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产品名称

sSPhos,

Quality Level

100

product line

Buchwald Ligand

form

solid

reaction suitability

reaction type: Cross Couplings, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

functional group

phosphine

SMILES string

O.[Na+].COc1ccc(c(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4)S([O-])(=O)=O

InChI

1S/C26H35O5PS.Na.H2O/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);;1H2/q;+1;/p-1

InChI key

MAPQBSXKBDVINV-UHFFFAOYSA-M

Application

了解有关Buchwald 膦配体的更多信息。

Legal Information

用法以美国专利 6307087 和 6395916 为准。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCM9711
MKCM7560
MKCG0279
MKBW6781V
MKBW6779V

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商品

Buchwald Phosphine Ligands

Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

Buchwald Phosphine Ligands

Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

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Phosphine Ligand Application Guide

General catalysts for the Suzuki-Miyaura and Sonogashira coupling reactions of aryl chlorides and for the coupling of challenging substrate combinations in water.
Kevin W Anderson et al.
Angewandte Chemie (International ed. in English), 44(38), 6173-6177 (2005-08-13)
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
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Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
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全球贸易项目编号

货号GTIN
677280-10G04061833338346
677280-2G04061833549728
677280-500MG04061833549735