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[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)

powder

别名:

Pd(dppf)Cl2

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关于此项目

线性分子式:
(C17H14P)2Fe · PdCl2
化学文摘社编号:
72287-26-4
分子量:
731.70
NACRES:
NA.22
PubChem Substance ID:
329761901
UNSPSC Code:
12161600
EC Number:
460-040-3
MDL number:
MFCD00015757
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产品名称

[1,1′-双(二苯基膦)二茂铁]二氯化钯(II),

form

powder

Quality Level

200

reaction suitability

core: palladium, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction

mp

266-283 °C (lit.)

SMILES string

[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2

InChI key

JCWIWBWXCVGEAN-UHFFFAOYSA-L

Application

Pd(dppf)Cl2可作为有效的钯催化剂用于以下反应：
  • 仲烷基和正烷基格氏试剂的交叉偶联，产率和选择性高。
  • 芳基硼酸酯与[11C]甲基碘进行Suzuki偶联反应，形成官能化[11C]甲苯衍生物。
  • 1,3,5-三溴苯与格氏试剂进行Kumada交叉偶联反应，形成星形低聚噻吩。
对于小规模和高通量应用，可选用ChemBeads形式(919780)
钯催化交叉偶联反应应用指南
用于C-C和C-N偶联反应的催化剂。

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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBK8108
SHBK8030
SHBK8036
SHBK8035
SHBK8034

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商品

Syntheses of Functionalized Alkenes, Arenes, and Cycloalkenes via a Hydroboration-Coupling Sequence

Tandem hydroboration Suzuki Coupling both intermolecular and intramolecular gave diverse alkyl substituted products dppf

Palladium-catalysed cyclisation of N-alkynyl aminomalonates.
Wilfried Hess et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(41), 12303-12306 (2010-09-15)
Shunsuke Chiba et al.
Journal of the American Chemical Society, 131(36), 12886-12887 (2009-08-25)
A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.
Electrophilic activation of benzaldehydes through ortho palladation: one-pot synthesis of 3-methylene-indan-1-ols through a domino allylstannylation/Heck reaction under neutral conditions.
Ján Cvengros et al.
Angewandte Chemie (International ed. in English), 48(33), 6148-6151 (2009-07-11)
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全球贸易项目编号

货号GTIN
697230-5G04061832786308
697230-1G04061832786131
697230-250G04061833550946
697230-25G04065271068131