Quality Level
assay
99.9%
form
powder
density
1.025 g/cm3 at 68 °F
SMILES string
[Na+].CC(C)(C)[O-]
InChI
1S/C4H9O.Na/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChI key
MFRIHAYPQRLWNB-UHFFFAOYSA-N
Application
叔丁醇钠可用作:
- 作为促进剂,促进芳香族化合物与卤代芳烃通过C-H键芳基化反应合成联芳基。
- 钯催化胺化反应中的碱。
- 作为碱,在钯催化剂存在的条件下,由未活化的芳基卤化物合成芳基 叔丁基醚。
- 参与 N-吲哚和 N-氮杂吲哚的去磺酰反应。
- 作为碱,用于烯烃和CO2合成丙烯酸钠。
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
57.2 °F
flash_point_c
14 °C
商品
Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.
tert-Butoxide-Mediated C-H Bond Arylation of Aromatic Compounds with Haloarenes
Yanagisawa S and Itami K
ChemCatChem, 3(5), 827-829 (2011)
Desulfonylation of Indoles and 7-Azaindoles Using Sodium tert-Butoxide
Chaulet C, et al.
Synlett, 2010(10), 1481-1484 (2010)
Palladium-catalyzed formation of aryl tert-butyl ethers from unactivated aryl halides
Parrish CA and Buchwald SL
The Journal of Organic Chemistry, 66(7), 2498-2500 (2001)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 703788-25G | 04061833390320 |
| 703788-5G | 04061833490716 |

