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707589

氯-（2-二环己基膦-2′,6′-双异丙氧基-1,1′-联苯） [2-（2-氨乙基）苯基] 钯 (Ⅱ)-甲基--叔 -丁醚加合物

95%, solid

别名:

(RuPhos) 钯 (II) 氯化苯乙胺（1:1 MTBE 溶剂化物）, RuPhos Palladacycle, RuPhos 预催化剂

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关于此项目

经验公式（希尔记法）:
C38H53ClNO2PPd · CH3OC4H9
化学文摘社编号:
2361069-97-6
分子量:
816.83
UNSPSC Code:
12161600
PubChem Substance ID:
329762732
NACRES:
NA.22
MDL number:
MFCD12545955
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产品名称

氯-（2-二环己基膦-2′,6′-双异丙氧基-1,1′-联苯） [2-（2-氨乙基）苯基] 钯 (Ⅱ)-甲基--叔 -丁醚加合物, 95%

Quality Level

100

product line

Buchwald precatalyst Generation 1

assay

95%

form

solid

feature

generation 1

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

180-200 °C

functional group

phosphine

SMILES string

COC(C)(C)C.NCCc1ccccc1[Pd]Cl.CC(C)Oc2cccc(OC(C)C)c2-c3ccccc3P(C4CCCCC4)C5CCCCC5

InChI

1S/C30H43O2P.C8H10N.C5H12O.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-4H,6-7,9H2;1-4H3;1H;/q;;;;+1/p-1

InChI key

OMMPYFRVDWZBNR-UHFFFAOYSA-M

Application

钯催化交叉偶联反应的应用指南
用于 Buchwald-Hartwig 胺化反应的催化剂。

Legal Information

用法以美国专利 6307087 和 6395916 为准。

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H314,H335

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBD6094V
SHBB4745V
42096TM
63996DK

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Buchwald Portfolio - Precatalysts and Ligands

Buchwald Portfolio: Palladacycles and Ligands

Mark R Biscoe et al.
Journal of the American Chemical Society, 130(21), 6686-6687 (2008-05-02)
A new class of one-component Pd precatalysts bearing biarylphosphine ligands is described. These precatalysts are air- and thermally stable, are easily activated under normal reaction conditions at or below room temperature, and ensure the formation of the highly active monoligated
Jaclyn L Henderson et al.
Organic letters, 12(20), 4438-4441 (2010-09-24)
Simple and efficient procedures for the Pd-catalyzed cross-coupling of primary and secondary amines with halo-7-azaindoles(pyrrolo[2,3-b]pyridine) are presented. Previously, no general method was available to ensure the highly selective reaction of the heteroaryl halide in the presence of the unprotected azaindole
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Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
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全球贸易项目编号

货号GTIN
707589-1G04061832843025
707589-250MG04061833551325