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745979

tbuttphos Pd G3

96%, solid

别名:

叔 -BuBrettPhos-Pd-G3, [（2-二-叔-丁基膦-3,6-二甲氧基-2′,4′,6′-三异丙基-1,1′-联苯）-2-（2′-氨基-1,1′-联苯）] 甲磺酸钯 (II)

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关于此项目

经验公式（希尔记法）:
C44H62NO5PPdS
化学文摘社编号:
1536473-72-9
分子量:
854.43
UNSPSC Code:
12161600
PubChem Substance ID:
329765730
NACRES:
NA.22
MDL number:
MFCD25976528
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产品名称

tbuttphos Pd G3, 96%

Quality Level

100

product line

Buchwald precatalyst Generation 3

assay

96%

form

solid

feature

generation 3

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

119-131 °C

functional group

phosphine

SMILES string

COC1=CC=C(C(P(C(C)(C)C)C(C)(C)C)=C1C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C)OC.NC3=C(C=CC=C3)C4=C(C=CC=C4)[Pd]OS(C)(=O)=O

InChI

1S/C31H49O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-23(20(3)4)27(24(18-22)21(5)6)28-25(32-13)15-16-26(33-14)29(28)34(30(7,8)9)31(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

GAQPAUHHECNHNS-UHFFFAOYSA-M

General description

tBuBrettPhos Pd G3 是第三代 (G3) Buchwald 预催化剂，可用于交叉偶联反应，形成 C-C、C-N、C-O、C-F、C-CF3 和 C-S 键。它具有空气、水分和热稳定性，可溶于多种常见有机溶剂。它具有催化剂用量少、反应时间短、能有效地形成活性物种和精确控制配体钯比等特点。

Application

tBuBrettPhos Pd G3 已被用作在温和反应条件下氨基酸酯与芳基三氟甲磺酸酯的 N -芳基化的预催化剂，且氨基酸酯的消旋作用极小。它也可用于在苯甲醛肟作为氢氧化物替代物存在下催化芳基卤化物转化为酚类。

对于小规模和高通量应用，产品为 ChemBeads (928313)

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBN5085
SHBM0165
SHBK8065
SHBL1146
SHBJ7055

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全球贸易项目编号

货号GTIN
745979-100MG04061832970301
745979-2G04061832970318
745979-1G04061832890227
745979-500MG04061832970325
745979-5G04061832970332