747130
Josiphos SL-J009-1 Pd G3
solid
别名:
Josiphos SL-J009-1-G3-环钯配合物, {(R)-1-[(Sp)-2-(二环己基膦基)二茂铁基]乙基二-叔丁基膦}[2-(2′-氨基-1,1′-联苯基)]钯(II) 甲磺酸盐
选择尺寸
关于此项目
产品名称
Josiphos SL-J009-1 Pd G3,
Quality Level
product line
Buchwald precatalyst Generation 3
form
solid
feature
generation 3
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp
180-186 °C
functional group
phosphine
SMILES string
NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.C[C@@H](P(C(C)(C)C)C(C)(C)C)[C]3[C](P(C4CCCCC4)C5CCCCC5)[C][C][C]3.[C]6[C][C][C][C]6.[Fe]
InChI
1S/C27H47P2.C12H10N.C5H5.CH4O3S.Fe.Pd/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-2-4-5-3-1;1-5(2,3)4;;/h14,19-23H,8-13,15-18H2,1-7H3;1-6,8-9H,13H2;1-5H;1H3,(H,2,3,4);;/q;;;;;+1/p-1/t21-;;;;;/m1...../s1
InChI key
GJFJVCUFUWXFEB-RPDSBUJNSA-M
General description
Application
- N-Paspaline和N-Emindole PB的全合成： 讨论如何使用包括 RuPhos 和 Josiphos 配体在内的各种催化剂合成复杂分子结构（Radical-Polar Crossover Cyclizations, 2020）。
- 无保护吲唑对开环异构化的耐受性：前处理中催化C-S偶联的案例研究： 利用Josiphos SL-J009-1 Pd-G3在强碱条件下催化C-S偶联反应（The Journal of Organic Chemistry, 2017）。
- 异丙基BippyPhos预催化剂的合成与表征： 比较各种磷化氢配体，包括XPhos和Josiphos在有机合成中的催化活性（Tetrahedron, 2022）。
- 新型PqsR群体感应抑制剂： 介绍Josiphos配体在潜在药物化合物合成中的实验使用（2020, University of Saarland）。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
G3和G4 Buchwald预催化剂是一类最新的空气、湿度和热稳定型交叉偶联复合物，可用于键形成以实现其多功能性和高反应性。
All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
相关内容
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全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 747130-5G | 04061832970363 |
| 747130-100MG | 04061832970349 |
| 747130-1G | 04061826251690 |
| 747130-250MG | 04061832970356 |