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761435

[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)甲磺酸酯

greener alternative

95%, solid

别名:

[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II) 甲磺酸酯, cataCXium-A-Pd-G3, 甲磺酸[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)

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关于此项目

经验公式（希尔记法）:
C37H52NO3PPdS
化学文摘社编号:
1651823-59-4
分子量:
728.27
UNSPSC Code:
12352300
PubChem Substance ID:
329766937
NACRES:
NA.22
Assay:
95%
Form:
solid
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产品名称

[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)甲磺酸酯, 95%

Quality Level

100

product line

Buchwald precatalyst Generation 3

assay

95%

form

solid

feature

generation 3

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

greener alternative product score

old score: 16
new score: 2
Find out more about DOZN™ Scoring

greener alternative product characteristics

Waste Prevention
Atom Economy
Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤3% acetone

mp

196-241 °C (decomposition)

functional group

phosphine

greener alternative category

Re-engineered

SMILES string

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7

InChI

1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;

InChI key

REYVZCOGMIXVNX-DVBMAMJVSA-M

General description

我们竭诚为您带来满足绿色替代产品四大类别要求的替代产品。 本产品属于重新设计产品类别，在绿色化学原理“防止废弃物”、“更安全的溶剂和助剂”以及“原子经济”方面有重大改进。点击此处查看其 DOZN 记分卡。

Application

cataCXium® A Pd G3 是一种第三代Buchwald预催化剂，可用于：
  • 吡啶羧酸的直接邻位芳基化。
  • 催化Suzuki–Miyaura交叉偶联反应，以合成1-杂芳基-3-氮杂双环[3.1.0]己烷。
  • 炔烃的钯催化羰基碳全氟烷基化。
  • 各种 gem二取代环丙烷的合成过程中成对二(溴基)环丙烷的Suzuki–Miyaura 偶联反应。
  • 末端炔烃的溴全氟烷基化。
  • 芳香卤化物和炔烃的无铜Sonogashira 偶联反应，以形成 C-C键。
  • 有机三氟硼酸盐和芳基卤化物的Suzuki 交叉偶联反应。
对于小规模和高通量用途，产品为ChemBeads ChemBeads (928305)

Legal Information

cataCXium is a registered trademark of Umicore AG & Co. KG

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBN8280
SHBM8322
SHBM1003
SHBL9524
SHBK7459

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商品

G3和G4 Buchwald预催化剂

G3和G4 Buchwald预催化剂是一类最新的空气、湿度和热稳定型交叉偶联复合物，可用于键形成以实现其多功能性和高反应性。

G3 and G4 Buchwald Precatalysts

G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.

Scale-Up Guide: Suzuki-Miyaura Cross-Coupling Reaction

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form.

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全球贸易项目编号

货号GTIN
761435-250MG04061832970622
761435-5G04061832970639
761435-1G04061826251935
761435-25G04065271045330