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Merck
CN

791016

RockPhos

97%, solid

别名:

2-二(叔丁基)膦基-2′,4′,6′-三异丙基-3-甲氧基-6-甲基联苯, 二叔丁基(2′,4′,6′-三异丙基-3-甲氧基-6-甲基-[1,1′-联苯] -2-基)膦

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关于此项目

经验公式(希尔记法):
C31H49OP
化学文摘社编号:
分子量:
468.69
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

RockPhos, 97%

Quality Level

product line

Buchwald Ligand

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings

mp

121-131 °C

functional group

phosphine

storage temp.

15-25°C

SMILES string

CC1=C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)C(P(C(C)(C)C)C(C)(C)C)=C(OC)C=C1

InChI

1S/C31H49OP/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13/h15-21H,1-14H3

InChI key

CVLLAKCGAFNZHJ-UHFFFAOYSA-N

Application

RockPhos是一种联苯基膦配体,与Pd(0) 催化剂一起用于碳-碳和碳-杂原子键的形成反应。
它也可用于以下反应:
  • 在钯催化剂存在的情况下进行溴查耳酮的2-氟乙氧基化。
  • 以RockPhos Pd G3为催化剂将芳基氯化物转化为芳基甲醇盐。



存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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全球贸易项目编号

货号GTIN
791016-500MG04061833242919
791016-2G04061833341001