产品名称
硝基化合物的还原反应用Fe/ppm Pd,
form
solid
Quality Level
composition
FeCl2 (372870), 23.3-27.4 wt. % , MgCl2 (M8266), 15.3-18.8 wt. % , Pd (203939), <0.3 wt. % , THF (186562), 53.5-61.6 wt. %
reaction suitability
core: iron, reagent type: catalyst
storage temp.
2-8°C
SMILES string
[Fe](Cl)(Cl)Cl
InChI key
RBTARNINKXHZNM-UHFFFAOYSA-K
Application
When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.
Other Notes
Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead
From milligrams to kilograms: synthetic chemistry following nature′s lead
Disclaimer
Handle under nitrogen and store under argon in refrigerator.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F
flash_point_c
-17 °C
法规信息
危险化学品
此项目有
相关内容
Designer surfactants enable diverse transformations like Suzuki-Miyaura, Olefin Metathesis, and 1,4-Addition to Enones in water by Prof. Bruce Lipshutz.
Switching from organic solvents to water at an industrial scale.
Parmentier M, et al.
Current opinion in green and sustainable chemistry., 7, 13-17 (2017)
When Does Organic Chemistry Follow Nature?s Lead and ?Make the Switch?.
Lipshutz B H
The Journal of Organic Chemistry, 82(6), 2806-2816 (2017)
New surfactants for chemistry in water.
Krause N
Current opinion in green and sustainable chemistry., 7, 18-22 (2017)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 809330-500MG | 04061833244043 |