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900275

(t-Bu)PhCPhos

95%, powder or crystals

别名:

2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl

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关于此项目

经验公式（希尔记法）:
C26H33N2P
化学文摘社编号:
1660153-91-2
分子量:
404.53
MDL number:
MFCD29905429
UNSPSC Code:
12352200
NACRES:
NA.22
Assay:
95%
Form:
powder or crystals
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产品名称

(t-Bu)PhCPhos, 95%

Quality Level

100

product line

Buchwald Ligand

assay

95%

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand

mp

112 °C

functional group

phosphine

SMILES string

P(C(C)(C)C)(c2c(cccc2)c3c(cccc3N(C)C)N(C)C)c1ccccc1

InChI

1S/C26H33N2P/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7/h8-19H,1-7H3

InChI key

HTHOMNNVAUPLKK-UHFFFAOYSA-N

Application

(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Paula Ruiz-Castillo et al.
Journal of the American Chemical Society, 137(8), 3085-3092 (2015-02-05)
We report the Pd-catalyzed arylation of very hindered α,α,α-trisubstituted primary amines. Kinetics-based mechanistic analysis and rational design have led to the development of two biarylphosphine ligands that allow the transformation to proceed with excellent efficiency. The process was effective in

全球贸易项目编号

货号GTIN
900275-1G04061826655948
900275-250MG04061833244289