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912395

NaBHT

Name: NaBHT
Brand: ALDRICH

别名:

Sodium butylated hydroxytoluene

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关于此项目

经验公式（希尔记法）:

C₁₅H₂₃NaO

化学文摘社编号:

16654-89-0

分子量:

242.33

UNSPSC Code:

12352111

NACRES:

NA.22

MDL number:

MFCD30474994

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属性

form

powder

Quality Level

100

storage temp.

−20°C

SMILES string

[Na+].[O-]c1c(cc(cc1C(C)(C)C)C)C(C)(C)C

InChI

1S/C15H24O.Na/c1-10-8-11(14(2,3)4)13(16)12(9-10)15(5,6)7;/h8-9,16H,1-7H3;/q;+1/p-1

InChI key

AOIQNBCUUALSSZ-UHFFFAOYSA-M

说明

Application

NaBHT is an organic soluble base used for the Pd-catalyzed arylation of base-sensitve amines with aryl halides. NaBHT has also been show to be an efficient hydride source for the Pd-catalyzed reduction of aryl halides.

Other Notes

Sodium Butylated Hydroxytoluene (NaBHT) as a New and Efficient Hydride Source for Pd-Catalysed Reduction Reactions

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Selective Monoarylation of Primary Amines Using the Pd-PEPPSI-IPent(Cl) Precatalyst.

Sepideh Sharif et al.

Angewandte Chemie (International ed. in English), 54(33), 9507-9511 (2015-06-23)

A single set of reaction conditions for the palladium-catalyzed amination of a wide variety of (hetero)aryl halides using primary alkyl amines has been developed. By combining the exceptionally high reactivity of the Pd-PEPPSI-IPent(Cl) catalyst (PEPPSI=pyridine enhanced precatalyst preparation, stabilization, and

Sodium Butylated Hydroxytoluene (NaBHT) as a New and Efficient Hydride Source for Pd-Catalysed Reduction Reactions.