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916129

1,10-Phenanthroline nickel (ll) dichloride

powder or crystals

别名:

phenNiCl2

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关于此项目

经验公式（希尔记法）:
C12H8Cl2N2Ni
化学文摘社编号:
22980-76-3
分子量:
309.80
MDL number:
MFCD32706956
UNSPSC Code:
12352200
NACRES:
NA.22
Form:
powder or crystals
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产品名称

1,10-Phenanthroline nickel (ll) dichloride,

form

powder or crystals

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

[Ni].Cl.Cl.n1c2c3ncccc3ccc2ccc1

InChI

1S/C12H8N2.2ClH.Ni/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;

InChI key

CHVPLVVTLIMTJX-UHFFFAOYSA-N

Application

1,10-Phenanthroline nickel (ll) dichloride is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.

Other Notes

Regioselective Single-Electron Tsuji-Trost Reaction of Allylic Alcohols: A Photoredox/Nickel Dual Catalytic Approach

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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Zheng-Jun Wang et al.
Organic letters, 21(16), 6543-6547 (2019-08-08)
A radical-mediated functionalization of allyl alcohol derived partners with a variety of alkyl 1,4-dihydropyridines via photoredox/nickel dual catalysis is described. This transformation transpires with high linear and E-selectivity, avoiding the requirement of harsh conditions (e.g., strong base, elevated temperature). Additionally

全球贸易项目编号

货号GTIN
916129-1G04061842287000
916129-5G04061842287017