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924245

Deoxazole

≥95%, powder

别名:

5,7-Di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium tetrafluoroborate

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关于此项目

经验公式（希尔记法）:
C21H26BF4NO
化学文摘社编号:
1207294-92-5
分子量:
395.24
MDL number:
MFCD24713435
NACRES:
NA.22
UNSPSC Code:
12161600
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产品名称

Deoxazole, ≥95%

Quality Level

100

assay

≥95%

form

powder

mp

215-219 °C

Application

Deoxazole is an N-heterocyclic carbene salt which activates free alcohols for a C-C cross coupling reaction with aryl halides. The MacMillan group developed a mild, robust, and selective metallaphotoredox-based cross-coupling platform for the deoxygenative coupling for free alcohols using Deoxazole, a Ni catalyst, and [Ir(dtbbpy)(ppy)2]PF6.

Other Notes

Metallaphotoredox-enabled deoxygenative arylation of alcohols

存储类别

11 - Combustible Solids

wgk

WGK 3

历史批次信息供参考:

分析证书(COA)

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Zhe Dong et al.
Nature, 598(7881), 451-456 (2021-09-01)
Metal-catalysed cross-couplings are a mainstay of organic synthesis and are widely used for the formation of C-C bonds, particularly in the production of unsaturated scaffolds1. However, alkyl cross-couplings using native sp3-hybridized functional groups such as alcohols remain relatively underdeveloped2. In particular

全球贸易项目编号

货号GTIN
924245-5G04065267470979
924245-1G04065267470962